The given electron configuration represents the ground state or an excited state of the atom has to be determined. Figure 1 Concept Introduction: Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired. If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital. If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

Question

Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 1

Question

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Q: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCC

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Answer 2

Question

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

Answer 7

Chapter 1, Problem 1E.7E

(a)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 1

Concept Introduction:

Electrons are filled in each orbital one after another in the increasing order of energy. While filling the orbitals, more than two electrons can be placed in an orbital. And also, the spin of the two electron in the same orbital must be paired.

If there are more than one orbitals in a subshell are available for filling the electron, then electrons with parallel spin goes to different subshell rather than pairing two electrons in one orbital.

If an atom having electrons in energy states higher than predicted by the above rules then it is said to be in an excited state.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

Answer 14

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Answer 25

Ch. 1 - Prob. 1A.1AST Ch. 1 - Prob. 1A.1BST Ch. 1 - Prob. 1A.2AST Ch. 1 - Prob. 1A.2BST Ch. 1 - Prob. 1A.1E Ch. 1 - Prob. 1A.3E Ch. 1 - Prob. 1A.4E Ch. 1 - Prob. 1A.5E Ch. 1 - Prob. 1A.6E Ch. 1 - Prob. 1A.7E

Solution Summary: The author explains that the electron configuration represents the ground state or an excited state of the atom.

Videos

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).

Chapter 1 Solutions

Solution Summary: The author explains that the electron configuration represents the ground state or an excited state of the atom.

Videos

Interpretation: The given electron configuration represents the ground state or an excited state of the atom has to be determined. Figure 2 Concept Introduction: Refer to part (a).

Interpretation: The given electron configuration represents the ground state or an excited state of the atom has to be determined. Figure 3 Concept Introduction: Refer to part (a).

Interpretation: The given electron configuration represents the ground state or an excited state of the atom has to be determined. Figure 4 Concept Introduction: Refer to part (a).

Chapter 1 Solutions

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 2

Concept Introduction:

Refer to part (a).

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 3

Concept Introduction:

Refer to part (a).

Interpretation:

The given electron configuration represents the ground state or an excited state of the atom has to be determined.

Figure 4

Concept Introduction:

Refer to part (a).