Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 1, Problem 1B.17E
Interpretation Introduction
Interpretation:
The one who has shorter wavelength when running at the same speed: a person weighing
Concept Introduction:
de Broglie relation:
Mathematically, de Broglie relation can be represented as given below.
Where,
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In the following reaction, what quantity in moles of CH₃OH are required to give off 4111 kJ of heat? 2 CH₃OH (l) + 3 O₂ (g) → 2 CO₂ (g) + 4 H₂O(g) ∆H° = -1280. kJ
Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
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1400
1200
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800
Potential Energy (kJ)
600
400
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0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
Chapter 1 Solutions
Chemical Principles: The Quest for Insight
Ch. 1 - Prob. 1A.1ASTCh. 1 - Prob. 1A.1BSTCh. 1 - Prob. 1A.2ASTCh. 1 - Prob. 1A.2BSTCh. 1 - Prob. 1A.1ECh. 1 - Prob. 1A.3ECh. 1 - Prob. 1A.4ECh. 1 - Prob. 1A.5ECh. 1 - Prob. 1A.6ECh. 1 - Prob. 1A.7E
Ch. 1 - Prob. 1A.8ECh. 1 - Prob. 1A.9ECh. 1 - Prob. 1A.10ECh. 1 - Prob. 1A.11ECh. 1 - Prob. 1A.12ECh. 1 - Prob. 1A.13ECh. 1 - Prob. 1A.14ECh. 1 - Prob. 1A.15ECh. 1 - Prob. 1A.16ECh. 1 - Prob. 1A.17ECh. 1 - Prob. 1B.1ASTCh. 1 - Prob. 1B.1BSTCh. 1 - Prob. 1B.2ASTCh. 1 - Prob. 1B.2BSTCh. 1 - Prob. 1B.3ASTCh. 1 - Prob. 1B.3BSTCh. 1 - Prob. 1B.4ASTCh. 1 - Prob. 1B.4BSTCh. 1 - Prob. 1B.5ASTCh. 1 - Prob. 1B.5BSTCh. 1 - Prob. 1B.1ECh. 1 - Prob. 1B.2ECh. 1 - Prob. 1B.3ECh. 1 - Prob. 1B.4ECh. 1 - Prob. 1B.5ECh. 1 - Prob. 1B.6ECh. 1 - Prob. 1B.7ECh. 1 - Prob. 1B.8ECh. 1 - Prob. 1B.9ECh. 1 - Prob. 1B.10ECh. 1 - Prob. 1B.11ECh. 1 - Prob. 1B.12ECh. 1 - Prob. 1B.13ECh. 1 - Prob. 1B.14ECh. 1 - Prob. 1B.15ECh. 1 - Prob. 1B.16ECh. 1 - Prob. 1B.17ECh. 1 - Prob. 1B.18ECh. 1 - Prob. 1B.19ECh. 1 - Prob. 1B.21ECh. 1 - Prob. 1B.22ECh. 1 - Prob. 1B.23ECh. 1 - Prob. 1B.24ECh. 1 - Prob. 1B.25ECh. 1 - Prob. 1B.26ECh. 1 - Prob. 1B.27ECh. 1 - Prob. 1B.28ECh. 1 - Prob. 1C.1ASTCh. 1 - Prob. 1C.1BSTCh. 1 - Prob. 1C.1ECh. 1 - Prob. 1C.2ECh. 1 - Prob. 1C.3ECh. 1 - Prob. 1C.7ECh. 1 - Prob. 1D.1ASTCh. 1 - Prob. 1D.1BSTCh. 1 - Prob. 1D.2ASTCh. 1 - Prob. 1D.2BSTCh. 1 - Prob. 1D.1ECh. 1 - Prob. 1D.2ECh. 1 - Prob. 1D.3ECh. 1 - Prob. 1D.4ECh. 1 - Prob. 1D.5ECh. 1 - Prob. 1D.6ECh. 1 - Prob. 1D.7ECh. 1 - Prob. 1D.9ECh. 1 - Prob. 1D.10ECh. 1 - Prob. 1D.11ECh. 1 - Prob. 1D.12ECh. 1 - Prob. 1D.13ECh. 1 - Prob. 1D.14ECh. 1 - Prob. 1D.15ECh. 1 - Prob. 1D.16ECh. 1 - Prob. 1D.17ECh. 1 - Prob. 1D.18ECh. 1 - Prob. 1D.19ECh. 1 - Prob. 1D.20ECh. 1 - Prob. 1D.21ECh. 1 - Prob. 1D.22ECh. 1 - Prob. 1D.23ECh. 1 - Prob. 1D.24ECh. 1 - Prob. 1D.25ECh. 1 - Prob. 1D.26ECh. 1 - Prob. 1E.1ASTCh. 1 - Prob. 1E.1BSTCh. 1 - Prob. 1E.2ASTCh. 1 - Prob. 1E.2BSTCh. 1 - Prob. 1E.1ECh. 1 - Prob. 1E.2ECh. 1 - Prob. 1E.3ECh. 1 - Prob. 1E.4ECh. 1 - Prob. 1E.5ECh. 1 - Prob. 1E.7ECh. 1 - Prob. 1E.8ECh. 1 - Prob. 1E.9ECh. 1 - Prob. 1E.10ECh. 1 - Prob. 1E.11ECh. 1 - Prob. 1E.12ECh. 1 - Prob. 1E.13ECh. 1 - Prob. 1E.14ECh. 1 - Prob. 1E.15ECh. 1 - Prob. 1E.16ECh. 1 - Prob. 1E.17ECh. 1 - Prob. 1E.18ECh. 1 - Prob. 1E.19ECh. 1 - Prob. 1E.20ECh. 1 - Prob. 1E.21ECh. 1 - Prob. 1E.22ECh. 1 - Prob. 1E.23ECh. 1 - Prob. 1E.24ECh. 1 - Prob. 1E.25ECh. 1 - Prob. 1E.26ECh. 1 - Prob. 1F.1ASTCh. 1 - Prob. 1F.1BSTCh. 1 - Prob. 1F.2ASTCh. 1 - Prob. 1F.2BSTCh. 1 - Prob. 1F.3BSTCh. 1 - Prob. 1F.1ECh. 1 - Prob. 1F.2ECh. 1 - Prob. 1F.3ECh. 1 - Prob. 1F.4ECh. 1 - Prob. 1F.5ECh. 1 - Prob. 1F.6ECh. 1 - Prob. 1F.7ECh. 1 - Prob. 1F.8ECh. 1 - Prob. 1F.10ECh. 1 - Prob. 1F.11ECh. 1 - Prob. 1F.12ECh. 1 - Prob. 1F.13ECh. 1 - Prob. 1F.14ECh. 1 - Prob. 1F.15ECh. 1 - Prob. 1F.17ECh. 1 - Prob. 1F.18ECh. 1 - Prob. 1F.19ECh. 1 - Prob. 1F.22ECh. 1 - Prob. 1.1ECh. 1 - Prob. 1.2ECh. 1 - Prob. 1.3ECh. 1 - Prob. 1.9ECh. 1 - Prob. 1.10ECh. 1 - Prob. 1.11ECh. 1 - Prob. 1.12ECh. 1 - Prob. 1.13ECh. 1 - Prob. 1.14ECh. 1 - Prob. 1.15ECh. 1 - Prob. 1.17ECh. 1 - Prob. 1.19ECh. 1 - Prob. 1.21ECh. 1 - Prob. 1.22ECh. 1 - Prob. 1.23ECh. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - Prob. 1.27ECh. 1 - Prob. 1.28ECh. 1 - Prob. 1.31E
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