EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 1, Problem 1.93P
Interpretation Introduction
Interpretation:
The number of doses of aspirin prepared by the chemist is to be calculated.
Concept introduction:
Conversion factor is the numerical ratio that can be used to convert one set of units into another. To convert the units from one system to another the conversion factor ratio is written such that the unwanted units are canceled out.
The conversion factor to convert the milligrams to grams is as follows:
The conversion factor to convert the kilograms to grams is as follows:
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 1 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 1.1 - Prob. 1.1PCh. 1.2 - Characterize each process as a physical change or...Ch. 1.2 - Does the molecular art represent a chemical change...Ch. 1.3 - Classify each example of molecular art as a pure...Ch. 1.3 - Classify each item as a pure substance or a...Ch. 1.3 - Classify each item as an element or a compound:...Ch. 1.4 - What term is used for each of the following units:...Ch. 1.4 - If a nanometer is one-billionth of a meter...Ch. 1.4 - Prob. 1.9PCh. 1.4 - Using the prefixes in Table 1.2, determine which...
Ch. 1.5 - How many significant figures does each number...Ch. 1.5 - Indicate whether each zero in the following...Ch. 1.5 - Prob. 1.13PCh. 1.5 - Carry out each caluction and give the answer using...Ch. 1.5 - Carry out each calculation and give the answer...Ch. 1.6 - Lab results for a routine check-up showed an...Ch. 1.6 - Write each number in scientific notation. 93,200...Ch. 1.6 - Convert each number to its standard form. 6.5103...Ch. 1.7 - Write two conversion factors for each pair of...Ch. 1.7 - Prob. 1.20PCh. 1.7 - Carry out each of the following conversions. 25 L...Ch. 1.7 - What is the volume of liquid contained in the...Ch. 1.7 - Carry out each of the following conversions. 6,250...Ch. 1.8 - Prob. 1.24PCh. 1.8 - A patient is prescribed 0.100 mg of a drug that is...Ch. 1.8 - Prob. 1.26PCh. 1.9 - Prob. 1.27PCh. 1.9 - Prob. 1.28PCh. 1.10 - How does the mass of liquid A in cylinder [1]...Ch. 1.10 - Calculate the mass in grams of 10.0 mL of diethyl...Ch. 1.10 - If a 120-lb woman uses five 2.0lb lead weights in...Ch. 1.10 - If the density of a liquid is 0.80 g/mL, what is...Ch. 1 - Classify each example of molecular art as a pure...Ch. 1 - (a) Which representation(s) in Problem 1.19...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - Prob. 1.37PCh. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Classify each process as a chemical or physical...Ch. 1 - Prob. 1.41PCh. 1 - Prob. 1.42PCh. 1 - What is the temperature on the given Fahrenheit...Ch. 1 - a. What is the length of the given crayon in...Ch. 1 - What is the difference between an exact number and...Ch. 1 - Label each quantity as an exact or inexact number....Ch. 1 - Which quantity in each pair is larger? 5 mL or 5...Ch. 1 - Which quantity in each pair is larger? 10 km or 10...Ch. 1 - How many significant figures does each number...Ch. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Round each number ¡n Problem 1.51 to four...Ch. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Prob. 1.55PCh. 1 - Prob. 1.56PCh. 1 - Prob. 1.57PCh. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Rank the numbers in each group from smallest to...Ch. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - What is the volume of liquid contained in the...Ch. 1 - Prob. 1.65PCh. 1 - (a) If there are 15 mL in one tablespoon, how many...Ch. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Carry out each of the following conversions.
a....Ch. 1 - Carry out each of the following conversions.
a....Ch. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Which temperature in each pair is higher? a....Ch. 1 - Prob. 1.76PCh. 1 - Prob. 1.77PCh. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - If gasoline has a density of 0.66 g/mL, what is...Ch. 1 - Which is the upper layer when each of the...Ch. 1 - Prob. 1.84PCh. 1 - A lab test showed an individual’s chloesterol leve...Ch. 1 - Hemoglobin is a protein that transports oxygen...Ch. 1 - Prob. 1.87PCh. 1 - A soccer weighed 70.7 kg before a match, drank 1.8...Ch. 1 - Liposuction is a cosmetic procedure used to remove...Ch. 1 - A single 1-oz serving of tortilla chips contains...Ch. 1 - Prob. 1.91PCh. 1 - Prob. 1.92PCh. 1 - Prob. 1.93PCh. 1 - Prob. 1.94PCh. 1 - Prob. 1.95PCh. 1 - Prob. 1.96PCh. 1 - Often the specific amount of a drug to be...Ch. 1 - Prob. 1.98CPCh. 1 - Prob. 1.99CPCh. 1 - Prob. 1.100CPCh. 1 - Prob. 1.101CPCh. 1 - Prob. 1.102CPCh. 1 - Prob. 1.103CPCh. 1 - If the proper dosage of a medication is 10g/kg of...
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