
Concept explainers
(a)
Interpretation:
The answer of the given mathematical operation
Concept introduction:
During measurement of the physical quantity, there always occurs a digit that is not known with certainty. The significant digits carry significance for the measurement of that physical quantity.
There are certain thumb rules for identification of number of significant digits in a number.
1. All the trailing zeroes after the decimal point are not significant.
2. Zero that is placed to fix a decimal position is not significant.
3. Zero is only significant when it lies between two natural numbers.
For example, 0.00456 has three significant digits.
Rules for addition of significant figures are as follows:
While the addition or subtraction operation is being performed, operation is carried out and the final result is reported to least number of decimal places. Digits present at all the other places are rounded off.
While the multiplication or division operation is being performed, operation is carried out, and the result is reported to least number of significant digits. This means that the digits that follow the least number of significant digits are rounded off in the result.

Answer to Problem 1.53P
The answer upto two significant digits is22.
Explanation of Solution
The mathematical operation is carried out as follows:
Since two is the least number of significant digits that is present in 0.41, the product 21.976 must be rounded off so as to contain only two significant digits.
Therefore, the product is reported as 22.
(b)
Interpretation:
The difference of
Concept introduction:
During measurement of the physical quantity, there always occurs a digit that is not known with certainty. The significant digits carry significance for the measurement of that physical quantity.
There are certain thumb rules for identification of number of significant digits in a number.
1. All the trailing zeroes after the decimal point are not significant.
2. Zero that is placed to fix a decimal position is not significant.
3. Zero is only significant when it lies between two natural numbers.
For example, 0.00456 has three significant digits.
Rules for addition of significant figures are as follows:
While the addition or subtraction operation is being performed, operation is carried out and the final result is reported to least number of decimal places. Digits present at all the other places are rounded off.
While the multiplication or division operation is being performed, operation is carried out and the result is reported to least number of significant digits. This means that the digits that follow the least number of significant digits are rounded off in the result.

Answer to Problem 1.53P
The answer upto correct significant digit is 21.96.
Explanation of Solution
The mathematical operation is carried out as follows:
Since in addition or subtraction the result is reported that has least number of decimal places, all the other digits are rounded off.
Since two is the least number of decimal places that is present in 3.86, the digit 21.965 must be rounded off to contain only two decimal places.
Therefore, the difference is reported as 21.96.
(c)
Interpretation:
The quotient obtained on division of 65.2 by 12 is to be reported to appropriate number of significant figures.
Concept introduction:
During measurement of the physical quantity, there always occurs a digit that is not known with certainty. The significant digits carry significance for the measurement of that physical quantity.
There are certain thumb rules for identification of number of significant digits in a number.
1. All the trailing zeroes after the decimal point are not significant.
2. Zero that is placed to fix a decimal position is not significant.
3. Zero is only significant when it lies between two natural numbers.
For example, 0.00456 has three significant digits.
Rules for addition of significant figures are as follows:
While the addition or subtraction operation is being performed, operation is carried out and the final result is reported to least number of decimal places. Digits present at all the other places are rounded off.
While the multiplication or division operation is being performed, operation is carried out and the result is reported to least number of significant digits. This means the digits that follow the least number of significant digits are rounded off in the result.

Answer to Problem 1.53P
The answer upto two significant digits is 5.4.
Explanation of Solution
The mathematical operation is carried out as follows:
Since in division the result is reported that has least number of significant figures, all the other digits are rounded off.
Since two is the least number of significant digitsthat is present in 12, the product 5.4333 must be rounded off to contain only two significant digits.
Therefore, the quotient is reported as 5.4 correct upto two significant figures.
(d)
Interpretation:
The sum of
Concept introduction:
During measurement of the physical quantity, there always occurs a digit that is not known with certainty. The significant digits are digits that carry significance for the measurement of that physical quantity.
There are certain thumb rules for identification of number of significant digits in a number.
1. All the trailing zeroes after the decimal point are not significant.
2. Zero that is placed to fix a decimal position is not significant.
3. Zero is only significant when it lies between two natural numbers.
For example, 0.00456 has three significant digits.
Rules for addition of significant figures are as follows:
While the addition or subtraction operation is being performed, operation is carried out and the final result is reported to least number of decimal places. Digits present at all the other places are rounded off.
While the multiplication or division operation is being performed, operation is carried out and the result is reported to least number of significant digits. This means the digits that follow the least number of significant digits are rounded off in the result.

Answer to Problem 1.53P
The answer upto three significant digits is50.1.
Explanation of Solution
The mathematical operation is carried out as follows:
Since in addition or subtraction the result is reported that has least number of decimal places all the other digits are rounded off.
Since one is the least number of decimal places that is present in 41.0, the digit 3 must be rounded off to contain only one decimal place.
Therefore, the sum is reported as 50.1.
(e)
Interpretation:
The answer of the given mathematical operation
Concept introduction:
During measurement of the physical quantity, there always occurs a digit that is not known with certainty. The significant digits are digits that carry significance for the measurement of that physical quantity.
There are certain thumb rules for identification of number of significant digits in a number.
1. All the trailing zeroes after the decimal point are not significant.
2. Zero that is placed to fix a decimal position is not significant.
3. Zero is only significant when it lies between two natural numbers.
For example, 0.00456 has three significant digits.
Rules for addition of significant figures are as follows:
While the addition or subtraction operation is being performed, operation is carried out and the final result is reported to least number of decimal places. Digits present at all the other places are rounded off.
While the multiplication or division operation is being performed, operation is carried out and the result is reported to least number of significant digits. This means the digits that follow the least number of significant digits are rounded off in the result.

Answer to Problem 1.53P
The answer is reported as
Explanation of Solution
The mathematical operation is carried out as follows:
Since one is the least number of significant digits that is present in 0.2and hence the product 130.84 must be rounded off so as to contain only one significant digit.
Therefore, the product is reported as
(f)
Interpretation:
The difference of
Concept introduction:
Rules for addition of significant figures are as follows:
While the addition or subtraction operation is being performed, operation is carried out and the final result is reported to least number of decimal places. Digits present at all the other places are rounded off.
While the multiplication or division operation is being performed, operation is carried out and the result is reported to least number of significant digits. This means the digits that follow the least number of significant digits are rounded off in the result.

Answer to Problem 1.53P
The answer upto two significant digits is1044.
Explanation of Solution
The mathematical operation is carried out as follows:
Since in addition or subtraction the result is reported that has least number of decimal places all the other digits are rounded off.
Since zero is the least number of decimal places that is present in 1045,the final result should contain zero decimal places.
Therefore, the difference is reported as 1044.
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Chapter 1 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning

