Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 1, Problem 16E
Interpretation Introduction
Interpretation:
The given changes are to be classified as physical and chemical change.
Concept introduction: Any change that does not affect the chemical composition of a substance is called physical change. It is a reversible change.
Any change that occurs by affecting the chemical composition of a substance resulting in the formation of new substance by the rearrangement of the atoms is called chemical change. It is an irreversible change.
To determine: The categorization of the given changes as a chemical or physical change.
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1600°
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In the diagram, the letter L indicates
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1400
8
1394°C
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2.14
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10000
912°C
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y + Fe3C
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1500
Cementite (Fe3C)
1000
4
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Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization
of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm").
Determine the following:
(a) molecular Formula and Degree of unsaturation of compound Brian
(b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts
(ii) integration, ciii) multiplicity and (iv) interferences made for each signal
(c) Draw the structure of compound Brian.
)
ΕΙ
43
41
27
71
114 (M+)
Hmmm
20
30
40
50 60
70
80
90 100 110 120
1H NMR spectrum
300 MHz in CDCl3
2.0
alle
1.0
Chapter 1 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 1 - For Practice 1.1 Is each change physical or...Ch. 1 - Prob. 1.2PCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.3MPCh. 1 - Record the temperature on the thermometer shown...Ch. 1 - For Practice 1.5 How many significant figures are...Ch. 1 - Perform the calculations to the correct number of...Ch. 1 - Prob. 1.7PCh. 1 - Convert 9255 cm3 to gallons.
Ch. 1 - Prob. 1.9P
Ch. 1 - Prob. 1.9MPCh. 1 - Backpackers often use canisters of white gas to...Ch. 1 - Prob. 1.10MPCh. 1 - For Practice 1.11
Find the radius (r)of an...Ch. 1 - Prob. 1.12PCh. 1 - Prob. 1SAQCh. 1 - Q2. This image represent a particulate view of a...Ch. 1 - Prob. 3SAQCh. 1 - Which property of rubbing alcohol is a chemical...Ch. 1 - Prob. 5SAQCh. 1 - Prob. 6SAQCh. 1 - Q7. Determine the mass of a 1.75 L sample of a...Ch. 1 - Prob. 8SAQCh. 1 - Q9. Perform the calculation to the correct number...Ch. 1 - Prob. 10SAQCh. 1 - Prob. 11SAQCh. 1 - Prob. 12SAQCh. 1 - Prob. 13SAQCh. 1 - Prob. 14SAQCh. 1 - Prob. 15SAQCh. 1 - 1. Classify each statement as an observation, a...Ch. 1 - Classify each statement as an observation, a law...Ch. 1 - A chemist decomposes several samples of carbon...Ch. 1 - 4. When astronomers observe distant galaxies, they...Ch. 1 - 5. Classify each substance as a pure substance or...Ch. 1 - 6. Classify each substance as a pure substance or...Ch. 1 - 7. Complete the table.
Substance Pure or...Ch. 1 - 8. Complete the table.
Substance Pure or...Ch. 1 - 9. Determine whether each molecular diagram...Ch. 1 - 10. Determine whether each molecular diagram...Ch. 1 - 11. Several properties of isopropyl alcohol (also...Ch. 1 - 12. Several properties of ozone (a pollutant in...Ch. 1 - 13. Classify each property as physical or chemical...Ch. 1 - 14. Classify each property as physical or...Ch. 1 - 15. Classify each change as physical or...Ch. 1 - 16. Classify each change as physical or chemical....Ch. 1 - 17. Based on the molecular digram, classify each...Ch. 1 - Based on the molecular diagram, classify each...Ch. 1 - 19. Convert each temperature.
a. 32 °F to °C...Ch. 1 - 20. Convert each temperature.
a. 212 °F to °C...Ch. 1 - 21. The coldest temperature ever measured m the...Ch. 1 - 22. The warmest temperature ever measured in the...Ch. 1 - 23. Use the prefix multipliers to express each...Ch. 1 - 24. Use scientific notation to express each...Ch. 1 - Complete the table: a. 1245kg 1.245106 g 1.245109...Ch. 1 - 26. Express the quantity 254,998 m in each unit....Ch. 1 - 27. How many 1 cm squares would it take to...Ch. 1 - 28. How many 1 cm cubes would it take to construct...Ch. 1 - 29. A new penny has a mass of 2.49 g and a volume...Ch. 1 - 30. A titanium bicycle frame displaces 0.314 L of...Ch. 1 - 31. Glycerol is a syrupy liquid often used in...Ch. 1 - 32. A supposedly gold nugget is tested to...Ch. 1 - 33. Ethylene glycol (antifreeze) has a density of...Ch. 1 - 34. Acetone (nail polish remover) Pies a density...Ch. 1 - 35. Read each measurment to the correct number of...Ch. 1 - Read each measurement to the correct number of...Ch. 1 - 37. For each measurement, underline the zeroes...Ch. 1 - 38. For each measurement underline the zeroes that...Ch. 1 - 39. How many significant figures are in each...Ch. 1 - 40. How many significant figures are in each...Ch. 1 - 41. Which quantities are exact numbers and...Ch. 1 - 42. Indicate the number of significant figures in...Ch. 1 - 43. Round each number to four significant...Ch. 1 - 44. Round each number to three significant...Ch. 1 - 45. Perform each calculation to the correct number...Ch. 1 - 46. Perform each calculation to the correct number...Ch. 1 - 47. Perform each calculation to the correct number...Ch. 1 - Prob. 48ECh. 1 - 49. Perform each calculation to the correct number...Ch. 1 - Prob. 50ECh. 1 - 51. A flask containing 117 mL of a liquid weighs...Ch. 1 - 51. A flask containing 11.7 mL of a liquid weighs...Ch. 1 - 53. Perform each unit conversion.
a. 27.8 L to cm3...Ch. 1 - 54. Perform each unit conversion.
a. 28.9 nm to ?m...Ch. 1 - 55. Perform each unit conversion between the...Ch. 1 - 56. Perform each unit conversion between the...Ch. 1 - 57. A runner wants to run 10.0 km at a pace of 7.5...Ch. 1 - 58. A cyclist rides at an average speed of 24...Ch. 1 -
59. A European automobile has a gas mileage of...Ch. 1 -
60. A gas can holds 5.0 gallons of gasoline....Ch. 1 - 61. A modest-sized house has an area of 195m2....Ch. 1 - 62. A bedroom has a volume of 115 m3. What is its...Ch. 1 - Prob. 63ECh. 1 - Total U.S. farmland occupies 954 million acres....Ch. 1 - Prob. 65ECh. 1 - Prob. 66ECh. 1 - Prob. 67ECh. 1 - Prob. 68ECh. 1 - 69. Classify each property as intensive or...Ch. 1 - 70. At what temperatures are the readings on the...Ch. 1 - 71. Suppose you have designed a new thermometer...Ch. 1 - On a new Jekyll temperature scale water freezes at...Ch. 1 - 73. Do each calculation without using your...Ch. 1 - 74. The value of the euro was recently $l.38 U.S....Ch. 1 - Prob. 75ECh. 1 - 76. The proton has a radius of approximately cm...Ch. 1 - Prob. 77ECh. 1 - Prob. 78ECh. 1 - Prob. 79ECh. 1 - Prob. 80ECh. 1 - Prob. 81ECh. 1 - Prob. 82ECh. 1 - The Toyota Prius, a hybrid electric vehicle, has...Ch. 1 - Prob. 84ECh. 1 - Prob. 85ECh. 1 - Prob. 86ECh. 1 - A length of #8 copper wire (radius = 1.63 mm) has...Ch. 1 - Prob. 88ECh. 1 - Prob. 89ECh. 1 - Prob. 90ECh. 1 - Prob. 91ECh. 1 - Prob. 92ECh. 1 - Nanotechnology, the field of building ultra-small...Ch. 1 - Prob. 94ECh. 1 - A box contains a mixture of small copper spheres...Ch. 1 - Prob. 96ECh. 1 - Prob. 97ECh. 1 - Prob. 98ECh. 1 - A cube has an edge length of 7 cm. If it is...Ch. 1 - Prob. 100ECh. 1 - For each box, examine the blocks attached to the...Ch. 1 - Prob. 102E
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