(a) Interpretation: Whether the given structure is a legitimate Lewis structure is to be determined. Concept introduction: For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2 nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

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Answer 1

Question

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

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PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS FOR THE MECHANISM!!! THANKS First image: QUESTION 6. I have to show, with ARROWS and STRUCTURES, the mechanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary. I also tried to draw the mechanism, tell me what to change. Please note that its an AMIDE thats formed not an AMINE the nitrogen has ONE hydrogen and one Phenyl-C-Phenyl. I already asked for this mechanism and got as a final product ...-NH2 not whats shown on the picture, thank you Ths second part. QUESTION 3. I just need a way to synthesize the lactone A, I already started please continue from where I left it Second image: I simply need the products, substrates or reagents, thank you

Indicate how to prepare a 10% sodium hydroxide (NaOH) solution to a slightly alkaline pH.

Answer 2

Question

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

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Answer 3

Question

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

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Answer 4

Question

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

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Answer 5

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 6

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 7

Chapter 1, Problem 1.45P

Interpretation Introduction

(a)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule, the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Whether the given structure is a legitimate Lewis structure is to be determined.

Concept introduction:

For a valid Lewis structure of a molecule the atoms must not exceed their normal valency. In general, this means atoms from the 2^nd row onward of the periodic table must follow the octet rule. The exceptions to this rule are elements from the third row like S, P, etc., which are capable of expanding their octets to a maximum of twelve valence electrons. A hydrogen atom cannot have more than two valence electrons.

Answer 16

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Answer 17

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Answer 26

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Answer 27

Ch. 1 - Prob. 1.1P Ch. 1 - Prob. 1.2P Ch. 1 - Prob. 1.3P Ch. 1 - Prob. 1.4P Ch. 1 - Prob. 1.5P Ch. 1 - Prob. 1.6P Ch. 1 - Prob. 1.7P Ch. 1 - Prob. 1.8P Ch. 1 - Prob. 1.9P Ch. 1 - Prob. 1.10P

Solution Summary: The author explains that the structure shown in part (a) is not a legitimate Lewis structure.

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Chapter 1 Solutions