(a) Interpretation: For the given ion, all the resonance structures are to be drawn. Concept introduction: If a molecule or ion has one of the following features, another resonance structure will exist: A lone pair on an atom adjacent to a multiple bond An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs. Alternating double/triple and single bonds. The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

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Answer 1

Question

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

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Calculating the pH at equivalence of a titration A chemist titrates 210.0 mL of a 0.1003 M hydrobromic acid (HBr) solution with 0.7550M KOH solution at 25 °C. Calculate the pH at equivalence. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added. pH = ] ☑ o0o 18 Ar

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Using the conditions of spontaneity to deduce the signs of AH and AS Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A This reaction is always spontaneous, but proceeds slower at temperatures above 120. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous except above 117. °C. AS is (pick one) ΔΗ is (pick one) This reaction is slower below 20. °C than C above. AS is |(pick one) ? 18 Ar 1

Answer 2

Question

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

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Answer 3

Question

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

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Answer 4

Question

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

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Answer 5

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 6

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 7

Chapter 1, Problem 1.29P

Interpretation Introduction

(a)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow, starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given ion, all the resonance structures are to be drawn.

Concept introduction:

If a molecule or ion has one of the following features, another resonance structure will exist:

A lone pair on an atom adjacent to a multiple bond

An atom with incomplete octet next to a multiple bond or next to an atom with one or more lone pairs.

Alternating double/triple and single bonds.

The movement of an electron pair is shown with a curved arrow starting at the pair and ending on the atom or region where it moves. The movement must be from a relatively electron rich atom or region to a relatively electron deficient atom or region.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 1 - Prob. 1.1P Ch. 1 - Prob. 1.2P Ch. 1 - Prob. 1.3P Ch. 1 - Prob. 1.4P Ch. 1 - Prob. 1.5P Ch. 1 - Prob. 1.6P Ch. 1 - Prob. 1.7P Ch. 1 - Prob. 1.8P Ch. 1 - Prob. 1.9P Ch. 1 - Prob. 1.10P

Solution Summary: The author explains that a molecule or ion can have resonance structures if it has an electron rich atom of the region adjacent

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