Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Textbook Question
Chapter 1, Problem 1.130E
What exponent or power of ten would you use to express how many meters are in a kilometer?
a.
b.
c.
d.
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Complete the following table. The only density needed is already given. Show your
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should be included and significant figures should be given close attention. Be sure to notice
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mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
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NO2
x
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F.W.
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Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 1 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 1 - A heavy steel ball is suspended by a thin wire....Ch. 1 - Explain how the following are related to each...Ch. 1 - Tell how you would try to prove to a doubter that...Ch. 1 - Prob. 1.4ECh. 1 - The attractive force of gravity for objetcs near...Ch. 1 - Earths rotation causes it to bulge at the equator....Ch. 1 - Classify each of the following as a physical or...Ch. 1 - Classify each of the following as a physical or...Ch. 1 - Classify each of the following properties as...Ch. 1 - Classify each of the following properties as...
Ch. 1 - A sample of liquid alcohol is frozen to a solid,...Ch. 1 - Succinic acid, a white solid that melts at 182C,...Ch. 1 - A sample of solid elemental phosphorus that is...Ch. 1 - Oxygen gas and solid carbon are both made up of...Ch. 1 - Under appropriate conditions, hydrogen peroxide...Ch. 1 - Water can be decomposed to hydrogen gas and oxygen...Ch. 1 - Methane gas, a component of natural gas, is burned...Ch. 1 - Classify each pure substance represented below by...Ch. 1 - Classify each pure substance represented below by...Ch. 1 - Consider the following experiments, and answer the...Ch. 1 - Early scientists incorrectly classified calcium...Ch. 1 - Classify each of the following as homogeneous or...Ch. 1 - Classify each of the following as homogeneous or...Ch. 1 - Classify as pure substance or solution each of the...Ch. 1 - Classify as pure substance or solution each of the...Ch. 1 - Prob. 1.26ECh. 1 - In the distant past, 1in. was defined as the...Ch. 1 - Prob. 1.28ECh. 1 - Which of the following quantities are expressed in...Ch. 1 - Which of the following quantities are expressed in...Ch. 1 - Prob. 1.31ECh. 1 - Prob. 1.32ECh. 1 - Referring only to Table 1.2, answer the following...Ch. 1 - Referring only to Table 1.2, answer the following...Ch. 1 - One inch is approximately equal to 2.54cm. Express...Ch. 1 - Cookbooks are going metric. In such books, 1 cup...Ch. 1 - Two cities in Germany are located 25km apart. What...Ch. 1 - The shotput used by female track and field...Ch. 1 - Referring to Table 1.3, answer the following...Ch. 1 - Prob. 1.40ECh. 1 - Prob. 1.41ECh. 1 - Using appropriate values from Table 1.3, answer...Ch. 1 - Prob. 1.43ECh. 1 - Prob. 1.44ECh. 1 - Prob. 1.45ECh. 1 - Which of the following numbers are written using...Ch. 1 - Which of the following numbers are written using...Ch. 1 - Write each of the following numbers using...Ch. 1 - Write each of the following numbers using...Ch. 1 - Prob. 1.50ECh. 1 - A sheet of paper is 0.0106cm, or 0.0042in., thick....Ch. 1 - Prob. 1.52ECh. 1 - Prob. 1.53ECh. 1 - Do the following multiplications, and express each...Ch. 1 - Prob. 1.55ECh. 1 - Prob. 1.56ECh. 1 - Express each of the following numbers using...Ch. 1 - Prob. 1.58ECh. 1 - Prob. 1.59ECh. 1 - Prob. 1.60ECh. 1 - Prob. 1.61ECh. 1 - Indicate to what decimal position readings should...Ch. 1 - Indicate to what decimal position readings should...Ch. 1 - Write the following measured quantities as you...Ch. 1 - Prob. 1.66ECh. 1 - Prob. 1.67ECh. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 1.69ECh. 1 - Do the following calculations and use the correct...Ch. 1 - Prob. 1.71ECh. 1 - Do the following calculations and use the correct...Ch. 1 - Prob. 1.73ECh. 1 - Do the following calculations and use the correct...Ch. 1 - Do the following calculations and use the correct...Ch. 1 - Prob. 1.76ECh. 1 - Determine a single factor derived from Table 1.3...Ch. 1 - Prob. 1.78ECh. 1 - Prob. 1.79ECh. 1 - Prob. 1.80ECh. 1 - Prob. 1.81ECh. 1 - A metric cookbook calls for 250mL of milk. Your...Ch. 1 - Prob. 1.83ECh. 1 - You have a 40-lb baggage limit for a transatlantic...Ch. 1 - You need 3.00lb of meat that sells for 3.41/lb...Ch. 1 - During a glucose tolerance test, the serum glucose...Ch. 1 - Prob. 1.87ECh. 1 - Prob. 1.88ECh. 1 - Prob. 1.89ECh. 1 - Prob. 1.90ECh. 1 - Prob. 1.91ECh. 1 - Immunoglobulin antibodies occur in five forms. A...Ch. 1 - Calculate the density of the following materials...Ch. 1 - Calculate the density of the following materials...Ch. 1 - Calculate the volume and density of a rectangular...Ch. 1 - Calculate the volume and density of a cube of lead...Ch. 1 - The volume of an irregularly shaped solid can be...Ch. 1 - The density of ether is 0.736g/mL. What is the...Ch. 1 - Calculate the mass in grams of 100.0mL of...Ch. 1 - Do the following metric system conversions by...Ch. 1 - A single water molecule has a mass of 2.991023g....Ch. 1 - Prob. 1.102ECh. 1 - Cooking oil has a density of 0.812g/mL. What is...Ch. 1 - Prob. 1.104ECh. 1 - At 4.0C, pure water has a density of 1.00g/mL. At...Ch. 1 - The following pairs of substances represent...Ch. 1 - Explain why a bathroom mirror becomes foggy when...Ch. 1 - Prob. 1.108ECh. 1 - Liquid mercury metal freezes to a solid at a...Ch. 1 - Prob. 1.110ECh. 1 - Show how the factor-unit method can be used to...Ch. 1 - Prob. 1.112ECh. 1 - Refer to Chemistry Around Us 1.2 and explain what...Ch. 1 - Prob. 1.114ECh. 1 - Which of the following properties is considered a...Ch. 1 - Which of the following properties depicts a...Ch. 1 - Which of the following is a mixture? a.sodium...Ch. 1 - Prob. 1.118ECh. 1 - Prob. 1.119ECh. 1 - The correct formula for converting Fahrenheit to...Ch. 1 - Prob. 1.121ECh. 1 - Prob. 1.122ECh. 1 - Prob. 1.123ECh. 1 - How many millimeters are there in one centimeter?...Ch. 1 - Convert 4.50102nm into pm. a.4.50102pm b.4.50102pm...Ch. 1 - Prob. 1.126ECh. 1 - Convert 4.50102nm into m. a.4.50102m b.4.501011m...Ch. 1 - The quantity 6185meters can be rewritten as: a....Ch. 1 - The number 1,000,000 is what power of 10? a. 106...Ch. 1 - What exponent or power of ten would you use to...Ch. 1 - Express 0.0562 in exponential notation. a....Ch. 1 - Write the correct answer correct number of...Ch. 1 - Prob. 1.133ECh. 1 - The percentage of oxygen by weight in Al2(SO4)3...Ch. 1 - Prob. 1.135ECh. 1 - The density of gold (Au) is 19.3g/cm3 and that of...
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