with amine concentration as shown below. A time-resolved laser spectroscopy experiment had also shown that the half-life of the phosphorescence in the absence of quencher is 29 us. What is the value of k,? [Q/(mmol dm) 1.0 5.0 10.0 I/(arbitrary units) 0.41 0.25 0.16 P17G.4 When benzophenone is exposed to ultraviolet radiation it is excited into a singlet state. This singlet changes rapidly into a triplet, which phosphoresces. Triethylamine acts as a quencher for the triplet. In an experiment in the solvent methanol, the phosphorescence intensity varied

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with amine concentration as shown below. A time-resolved laser spectroscopy
experiment had also shown that the half-life of the phosphorescence in the
absence of quencher is 29 us. What is the value of k,?
[Q/(mmol dm)
1.0
5.0
10.0
I/(arbitrary units)
0.41
0.25
0.16
P17G.4 When benzophenone is exposed to ultraviolet radiation it is
excited into a singlet state. This singlet changes rapidly into a triplet, which
phosphoresces. Triethylamine acts as a quencher for the triplet. In an
experiment in the solvent methanol, the phosphorescence intensity varied
Transcribed Image Text:with amine concentration as shown below. A time-resolved laser spectroscopy experiment had also shown that the half-life of the phosphorescence in the absence of quencher is 29 us. What is the value of k,? [Q/(mmol dm) 1.0 5.0 10.0 I/(arbitrary units) 0.41 0.25 0.16 P17G.4 When benzophenone is exposed to ultraviolet radiation it is excited into a singlet state. This singlet changes rapidly into a triplet, which phosphoresces. Triethylamine acts as a quencher for the triplet. In an experiment in the solvent methanol, the phosphorescence intensity varied
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