In an aqueous solution, the colourless weak acid p-nitrophenol (C,HşNO3) undergoes hydrolysis to produce yellow-coloured p-nitrophenoxide ions. The absorbance of this solution was measured at 410 nm and found to be 0.433 when using a sample cell with a pathlength of 1.00 cm. Only p-nitrophenoxide ions absorb at this wavelength. Its molar attenuation coefficient, at this wavelength, is 18 600 L molH cm-!. a) Complete the equilibrium equation. C,H,NO,(aq) + H,O() = (ад) + (аq) b) Determine the concentration of p-nitrophenoxide in the solution.
In an aqueous solution, the colourless weak acid p-nitrophenol (C,HşNO3) undergoes hydrolysis to produce yellow-coloured p-nitrophenoxide ions. The absorbance of this solution was measured at 410 nm and found to be 0.433 when using a sample cell with a pathlength of 1.00 cm. Only p-nitrophenoxide ions absorb at this wavelength. Its molar attenuation coefficient, at this wavelength, is 18 600 L molH cm-!. a) Complete the equilibrium equation. C,H,NO,(aq) + H,O() = (ад) + (аq) b) Determine the concentration of p-nitrophenoxide in the solution.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:6.
In an aqueous solution, the colourless weak acid p-nitrophenol (C,H5NO3) undergoes
hydrolysis to produce yellow-coloured p-nitrophenoxide ions.
The absorbance of this solution was measured at 410 nm and found to be 0.433 when
using a sample cell with a pathlength of 1.00 cm. Only p-nitrophenoxide ions absorb at
this wavelength. Its molar attenuation coefficient, at this wavelength, is 18 600 L mol¬
cm-!.
a) Complete the equilibrium equation.
CH,NO,(aq) + H,O(0) =
(aq) +
(aq)
b) Determine the concentration of p-nitrophenoxide in the solution.
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