Which three (3) substances in the table below of van der Waals constants would you expect to deviate most from ideal-gas behavior at low temperature and high pressure? Which three (3) other substances would deviate least? Explain. Substance а (L2 atm mol2) b (L mol1) Не 0.0341 0.02370 Ne 0.211 0.0171 Ar 1.34 0.0322 Kr 2.32 0.0398 Хе 4.19 0.0510 H2 0.244 0.0266 1.39 0.0391 N2 02 Cl2 H20 1.36 0.0318 6.49 0.0562 5.46 0.0305 CH4 2.25 0.0428 CO2 3.59 0.0427 CCI4 20.4 0.1383
Which three (3) substances in the table below of van der Waals constants would you expect to deviate most from ideal-gas behavior at low temperature and high pressure? Which three (3) other substances would deviate least? Explain. Substance а (L2 atm mol2) b (L mol1) Не 0.0341 0.02370 Ne 0.211 0.0171 Ar 1.34 0.0322 Kr 2.32 0.0398 Хе 4.19 0.0510 H2 0.244 0.0266 1.39 0.0391 N2 02 Cl2 H20 1.36 0.0318 6.49 0.0562 5.46 0.0305 CH4 2.25 0.0428 CO2 3.59 0.0427 CCI4 20.4 0.1383
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter1: Gases And The Zeroth Law Of Thermodynamics
Section: Chapter Questions
Problem 1.53E: At high temperatures, one of the van der Waals constants can be ignored. Which one? Justify your...
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Question
Which three (3) substances in the table below of van der Waals constants would you expect
to deviate most from ideal-gas behavior at low temperature and high pressure? Which three
(3) other substances would deviate least? Explain completely with solutions.
Transcribed Image Text:Which three (3) substances in the table below of van der Waals constants would you expect
to deviate most from ideal-gas behavior at low temperature and high pressure? Which three
(3) other substances would deviate least? Explain.
Substance
а (L? atm mol2)
b (L mol1)
Не
0.0341
0.02370
Ne
0.211
0.0171
Ar
1.34
0.0322
Kr
2.32
0.0398
Хе
4.19
0.0510
H2
0.244
0.0266
1.39
0.0391
N2
02
Cl2
H20
CH4
1.36
0.0318
6.49
0.0562
5.46
0.0305
2.25
0.0428
CO2
CCI4
3.59
0.0427
20.4
0.1383
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