Which of the following is a major product of the reaction sequence below? Br. (1) HNO3/H,SO, NO2 Br (A) H,CO. (B) H2CO. (2) Na®CH;0© CH:OH NO2 Br OCH3 Br (C) (D) rOCH3 NON. Compound C O Compound B Compound D Compound A
Which of the following is a major product of the reaction sequence below? Br. (1) HNO3/H,SO, NO2 Br (A) H,CO. (B) H2CO. (2) Na®CH;0© CH:OH NO2 Br OCH3 Br (C) (D) rOCH3 NON. Compound C O Compound B Compound D Compound A
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:**Question:**
Which of the following is a major product of the reaction sequence below?
**Reaction Sequence:**
Starting compound: Bromobenzene (C₆H₅Br)
1. \( \text{HNO}_3/\text{H}_2\text{SO}_4 \)
2. \( \text{Na}^+ \text{CH}_3\text{O}^- \) in methanol (\(\text{CH}_3\text{OH}\))
**Options:**
- Compound A: A benzene ring with a methoxy group (\(\text{OCH}_3\)) and a nitro group (\(\text{NO}_2\)) in the ortho position.
- Compound B: A benzene ring with a methoxy group (\(\text{OCH}_3\)) in the para position to a bromine atom.
- Compound C: A benzene ring with a bromine atom in the meta position to a methoxy group (\(\text{OCH}_3\)) and a nitro group (\(\text{NO}_2\)).
- Compound D: A benzene ring with a bromine atom in the ortho position to both a methoxy group (\(\text{OCH}_3\)) and a nitro group (\(\text{NO}_2\)).
**Answer Choices:**
- \( \bigcirc \) Compound C
- \( \bigcirc \) Compound B
- \( \bigcirc \) Compound D
- \( \bigcirc \) Compound A
**Explanation of the Reaction:**
This is a stepwise reaction involving nitration and nucleophilic aromatic substitution. Bromobenzene undergoes nitration with nitric acid (\(\text{HNO}_3\)) and sulfuric acid (\(\text{H}_2\text{SO}_4\)), introducing a nitro group. Then, the bromine atom is substituted by a methoxy group when treated with sodium methoxide (\(\text{Na}^+ \text{CH}_3\text{O}^-\)) in methanol.
Select the major product based on the position of substituents resulting from the reactions.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY