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Please fill in the blanks!! Which set of reagents (given below) would produce the products given in the following reaction? A Br₂, hv F NBS K heat B Br₂, DCM G H₂, Pd ? с HBr, DCM H Br₂, H₂O L Grubb's D HBr, H₂O KMnO4 E M CH₂1₂, Zn HBr, H₂O₂ 1. Li, 2. Cul

Please fill in the blanks!! Which set of reagents (given below) would produce the products given in the following reaction? A Br₂, hv F NBS K heat B Br₂, DCM G H₂, Pd ? с HBr, DCM H Br₂, H₂O L Grubb's D HBr, H₂O KMnO4 E M CH₂1₂, Zn HBr, H₂O₂ 1. Li, 2. Cul

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Educational Exercise: Identifying Reaction Reagents** **Task:** Determine which set of reagents will result in the conversion of the starting compound to the given product. **Reaction Overview:** - **Starting Compound:** Linear hydrocarbon with double bonds. - **Product:** Cyclized compound with two carbonyl groups. **Options for Reagents:** - **A:** \( \text{Br}_2, \text{hv} \) - **B:** \( \text{Br}_2, \text{DCM} \) - **C:** \( \text{HBr, DCM} \) - **D:** \( \text{HBr, H}_2\text{O} \) - **E:** \( \text{HBr, H}_2\text{O}_2 \) - **F:** \( \text{NBS} \) - **G:** \( \text{H}_2, \text{Pd} \) - **H:** \( \text{Br}_2, \text{H}_2\text{O} \) - **I:** \( \text{KMnO}_4 \) - **J:** \( 1. \text{Li}, 2. \text{CuI} \) - **K:** Heat - **L:** Grubb’s catalyst - **M:** \( \text{CH}_2\text{I}_2, \text{Zn} \) **Visual Description of the Reaction:** The starting compound has a linear arrangement with multiple double bonds. The product is a closed ring structure with two carbonyl groups suggesting an oxidative and cyclization process likely involving multiple steps. **Interpreting the Reagents:** - **Bromination and Halogenation (A, B, C, D, F, H):** Introducing bromine atoms to alkenes, potential for further substitutions. - **Reduction (G):** Saturating double bonds. - **Oxidation (I):** Transformations to carbonyl compounds. - **Cyclization and Coupling (J, L, M):** Form new C-C bonds potentially closing a ring structure. **Analysis of Possible Reaction Pathways:** To obtain the cyclic diketone from the linear diene: 1. The starting material needs an initial transformation to introduce functional groups. 2. Oxidative cleavage is necessary to form carbonyl groups. 3. Cycl
Transcribed Image Text:**Educational Exercise: Identifying Reaction Reagents** **Task:** Determine which set of reagents will result in the conversion of the starting compound to the given product. **Reaction Overview:** - **Starting Compound:** Linear hydrocarbon with double bonds. - **Product:** Cyclized compound with two carbonyl groups. **Options for Reagents:** - **A:** \( \text{Br}_2, \text{hv} \) - **B:** \( \text{Br}_2, \text{DCM} \) - **C:** \( \text{HBr, DCM} \) - **D:** \( \text{HBr, H}_2\text{O} \) - **E:** \( \text{HBr, H}_2\text{O}_2 \) - **F:** \( \text{NBS} \) - **G:** \( \text{H}_2, \text{Pd} \) - **H:** \( \text{Br}_2, \text{H}_2\text{O} \) - **I:** \( \text{KMnO}_4 \) - **J:** \( 1. \text{Li}, 2. \text{CuI} \) - **K:** Heat - **L:** Grubb’s catalyst - **M:** \( \text{CH}_2\text{I}_2, \text{Zn} \) **Visual Description of the Reaction:** The starting compound has a linear arrangement with multiple double bonds. The product is a closed ring structure with two carbonyl groups suggesting an oxidative and cyclization process likely involving multiple steps. **Interpreting the Reagents:** - **Bromination and Halogenation (A, B, C, D, F, H):** Introducing bromine atoms to alkenes, potential for further substitutions. - **Reduction (G):** Saturating double bonds. - **Oxidation (I):** Transformations to carbonyl compounds. - **Cyclization and Coupling (J, L, M):** Form new C-C bonds potentially closing a ring structure. **Analysis of Possible Reaction Pathways:** To obtain the cyclic diketone from the linear diene: 1. The starting material needs an initial transformation to introduce functional groups. 2. Oxidative cleavage is necessary to form carbonyl groups. 3. Cycl
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