Please fill in the blanks!! Which set of reagents (given below) would produce the products given in the following reaction? A Br₂, hv F NBS K heat B Br₂, DCM G H₂, Pd ? с HBr, DCM H Br₂, H₂O L Grubb's D HBr, H₂O KMnO4 E M CH₂1₂, Zn HBr, H₂O₂ 1. Li, 2. Cul
Please fill in the blanks!! Which set of reagents (given below) would produce the products given in the following reaction? A Br₂, hv F NBS K heat B Br₂, DCM G H₂, Pd ? с HBr, DCM H Br₂, H₂O L Grubb's D HBr, H₂O KMnO4 E M CH₂1₂, Zn HBr, H₂O₂ 1. Li, 2. Cul
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Educational Exercise: Identifying Reaction Reagents**
**Task:** Determine which set of reagents will result in the conversion of the starting compound to the given product.
**Reaction Overview:**
- **Starting Compound:** Linear hydrocarbon with double bonds.
- **Product:** Cyclized compound with two carbonyl groups.
**Options for Reagents:**
- **A:** \( \text{Br}_2, \text{hv} \)
- **B:** \( \text{Br}_2, \text{DCM} \)
- **C:** \( \text{HBr, DCM} \)
- **D:** \( \text{HBr, H}_2\text{O} \)
- **E:** \( \text{HBr, H}_2\text{O}_2 \)
- **F:** \( \text{NBS} \)
- **G:** \( \text{H}_2, \text{Pd} \)
- **H:** \( \text{Br}_2, \text{H}_2\text{O} \)
- **I:** \( \text{KMnO}_4 \)
- **J:** \( 1. \text{Li}, 2. \text{CuI} \)
- **K:** Heat
- **L:** Grubb’s catalyst
- **M:** \( \text{CH}_2\text{I}_2, \text{Zn} \)
**Visual Description of the Reaction:**
The starting compound has a linear arrangement with multiple double bonds. The product is a closed ring structure with two carbonyl groups suggesting an oxidative and cyclization process likely involving multiple steps.
**Interpreting the Reagents:**
- **Bromination and Halogenation (A, B, C, D, F, H):** Introducing bromine atoms to alkenes, potential for further substitutions.
- **Reduction (G):** Saturating double bonds.
- **Oxidation (I):** Transformations to carbonyl compounds.
- **Cyclization and Coupling (J, L, M):** Form new C-C bonds potentially closing a ring structure.
**Analysis of Possible Reaction Pathways:**
To obtain the cyclic diketone from the linear diene:
1. The starting material needs an initial transformation to introduce functional groups.
2. Oxidative cleavage is necessary to form carbonyl groups.
3. Cycl
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