What is the concentration solubility product constant (K'sp) for AGSCN in which the ionic strength (u) of solution is 0.050 M. (Ksp for AGSCN is 1.1x10-12) TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Cocfficient at Indicated lonic Strength lon a nm 0.001 0.005 0.01 0.05 0.1 H,O" Li, CH,COO Na', 10,, HSO, , HCO,, H,PO,, H,As0,, OAc OH",F, SCN , HS", CIO,", CIO,", BrO,, 10,", MnO,“ K', CI", Br, I, CN", NO,, NO,", HCOO Rb", C, TI", Ag", NH," Mg*, Be* Ca, Cu", Zn", Sn", Mn", Fe", N", Co*, Phthalate Sr", Ba", Cd, Hg*, s²- Ph", CO,, So,,C,O, Hg", So,, S,0,,Cr., HPO, AP, Fe", C", La'", Ce PO,, Fe(CN), Th, Z", Ce", Sn" Fe(CN), 0.9 0.967 0.934 0.913 0.85 0.83 0.6 0.966 0.930 0.907 0.83 0.80 0.4-0.45 0.965 0.927 0.902 0.82 0,7 0.35 0.965 0.926 0.900 0.81 0.76 0.965 0.965 0.872 0.925 0.925 0.756 0.748 0.743 0.3 0.899 0.81 0.75 0.897 0.690 0.25 0.80 0.75 0.8 0.52 0.44 0.6 0.870 0.676 0,48 0.40 0.5 0.869 0.668 0.46 0.38 0.45 0.868 0.741 0.665 0.45 0.36 0,40 0.867 0.738 0.661 0.44 0.35 0.9 0.737 0.540 0,443 0.24 0.18 0.4 0.726 0.505 0.394 0.252 0.16 0.095 0.063 1.1 0.587 0.348 0.10 0.5 0.569 0.305 0,200 0.047 0.020 O a. 6.30x10-10 O b. 1.28x10-12 O c. 2.30x10-11 O d. 1.40x10-12 O e. 1.70x10-12
What is the concentration solubility product constant (K'sp) for AGSCN in which the ionic strength (u) of solution is 0.050 M. (Ksp for AGSCN is 1.1x10-12) TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Cocfficient at Indicated lonic Strength lon a nm 0.001 0.005 0.01 0.05 0.1 H,O" Li, CH,COO Na', 10,, HSO, , HCO,, H,PO,, H,As0,, OAc OH",F, SCN , HS", CIO,", CIO,", BrO,, 10,", MnO,“ K', CI", Br, I, CN", NO,, NO,", HCOO Rb", C, TI", Ag", NH," Mg*, Be* Ca, Cu", Zn", Sn", Mn", Fe", N", Co*, Phthalate Sr", Ba", Cd, Hg*, s²- Ph", CO,, So,,C,O, Hg", So,, S,0,,Cr., HPO, AP, Fe", C", La'", Ce PO,, Fe(CN), Th, Z", Ce", Sn" Fe(CN), 0.9 0.967 0.934 0.913 0.85 0.83 0.6 0.966 0.930 0.907 0.83 0.80 0.4-0.45 0.965 0.927 0.902 0.82 0,7 0.35 0.965 0.926 0.900 0.81 0.76 0.965 0.965 0.872 0.925 0.925 0.756 0.748 0.743 0.3 0.899 0.81 0.75 0.897 0.690 0.25 0.80 0.75 0.8 0.52 0.44 0.6 0.870 0.676 0,48 0.40 0.5 0.869 0.668 0.46 0.38 0.45 0.868 0.741 0.665 0.45 0.36 0,40 0.867 0.738 0.661 0.44 0.35 0.9 0.737 0.540 0,443 0.24 0.18 0.4 0.726 0.505 0.394 0.252 0.16 0.095 0.063 1.1 0.587 0.348 0.10 0.5 0.569 0.305 0,200 0.047 0.020 O a. 6.30x10-10 O b. 1.28x10-12 O c. 2.30x10-11 O d. 1.40x10-12 O e. 1.70x10-12
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:What is the concentration solubility product constant (K'sp) for A9SCN in which the ionic strength (µ) of solution is 0.050 M. (Ksp for
AGSCN is 1.1x10-12)
TABLE 10-2
Activity Coefficients for Ions at 25°C
Activity Cocfficient at Indicated lonic Strength
Ion
0.001
0.005
0.01
0.05
0.1
0.85
H,O*
Li, C,H,COO"
Na" , I0,", HSO,", HCO," , H;PO, , H;AsO,, OAc
OH",F", SCN¯, HS", CIO,", CIO,", BrO,", IO,", MnO,
K*, CI", Br", I", CN", NO,",NO,", HCOO"
Rb*, Cs*, TI*, Ag*, NH,*
Mg*, Be*
Ca, Cu*, Zn³*, Sn²*, Mn²“, Fe²*, Ni³*, Co²*, Phthalate²-
Sr", Ba", Cd²*, Hg*, s²-
Ph", CO,, SO,,co,-
Hg,", SO,*¯, S,0,²-, C*, HPO,²-
A, Fe", C“, La", Ce*
PO,", Fe(CN),-
Th“, Zr*“, Ce**, Sn*
Fe(CN),
0.9
0.967
0.934
0.913
0.83
0.6
0.966
0.930
0.907
0.83
0.80
0.4-0.45
0.965
0.927
0.902
0.82
0.77
0.35
0.965
0.926
0.900
0.81
0.76
0.3
0.965
0.925
0.899
0.81
0.75
0.25
0.965
0.925
0.897
0,80
0.75
0.8
0.872
0.756
0.690
0.52
0.44
0.676
0.668
0.6
0.870
0.748
0.48
0.40
0.5
0.869
0.743
0.46
0.38
0.45
0.868
0.741
0.665
0.45
0.36
0,40
0,867
0.738
0.661
0,44
0.35
0.9
0.737
0.540
0.443
0.24
0.18
0.4
0.726
0.505
0.394
0.16
0.095
0.348
0.305
1.1
0.587
0.252
0.10
0.063
0.5
0.569
0.200
0.047
0.020
O a. 6.30x10-10
O b. 1.28x10-12
O c. 2.30x10-11
O d. 1.40x10-12
O e. 1.70x10-12
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