A solution of NaF is added dropwise to a solution that is 0.0168 M in Mg2+ and 2.53e-06 M in Y3+. The Ksp of MgF2 is 5.16e-11. The Ksp of YF3 is 8.62e-21. (a) What concentration of F- is necessary to begin precipitation? (Neglect volume changes.) [F-] = ______ M. (b) Which cation precipitates first? (c) What is the concentration of F- when the second cation begins to precipitate? [F-] = ________ M.

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A solution of NaF is added dropwise to a solution that is 0.0168 M in Mg2+ and 2.53e-06 M in Y3+.

The Ksp of MgF2 is 5.16e-11.

The Ksp of YF3 is 8.62e-21.

 

 

(a) What concentration of F- is necessary to begin precipitation? (Neglect volume changes.)

 

[F-] = ______ M.

 

 

(b) Which cation precipitates first?

 

 

(c) What is the concentration of F- when the second cation begins to precipitate?

 

[F-] = ________ M.

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