A solution of Na2CO3 is added dropwise to a solution that is 0.0553 M in Nd 3+ and 5.09e-09 M in H92²+. The Ksp of Nd2(CO3)3 is 1.08e-33. The Ksp of Hg2CO3 is 3.6e-17. (a) What concentration of CO32 is necessary to begin precipitation? (Neglect volume changes.) [0032] = M. (b) Which cation precipitates first? ○ Nd3+ 2+ OHg22 (c) What is the concentration of CO32- when the second cation begins to precipitate? [CO2]- M.

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A solution of Na2CO3 is added dropwise to a solution that is 0.0553 M in Nd 3+ and 5.09e-09 M in H92²+.
The Ksp of Nd2(CO3)3 is 1.08e-33.
The Ksp of Hg2CO3 is 3.6e-17.
(a) What concentration of CO32 is necessary to begin precipitation? (Neglect volume changes.)
[0032] =
M.
(b) Which cation precipitates first?
○ Nd3+
2+
OHg22
(c) What is the concentration of CO32- when the second cation begins to precipitate?
[CO2]-
M.
Transcribed Image Text:A solution of Na2CO3 is added dropwise to a solution that is 0.0553 M in Nd 3+ and 5.09e-09 M in H92²+. The Ksp of Nd2(CO3)3 is 1.08e-33. The Ksp of Hg2CO3 is 3.6e-17. (a) What concentration of CO32 is necessary to begin precipitation? (Neglect volume changes.) [0032] = M. (b) Which cation precipitates first? ○ Nd3+ 2+ OHg22 (c) What is the concentration of CO32- when the second cation begins to precipitate? [CO2]- M.
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