Treating the sigma bonds in boron trifluoride, BF3 as vectors, the following reducible representation were D3h E 2C3 3C2 on 2S3 30y Ired 3 1 3 1 To what symmetry representation labels does this reduces to? D E 2C3 3C2 2S3 30, A,' 1 ² + y?, z² Az' 1 -1 1 1 -1 R. E' 2 2 (x, y) (2 – y², xy) A," -1 A," -1 -1 -1 E" -1 -2 (R. R,) (xz, yz) O A2'+E' 2A1' + A2' O Aª"+E" O Aq'+E' 2.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter6: Quantum Mechanics And Molecular Structure
Section: Chapter Questions
Problem 39P: The photoelectron spectrum of HBr has two main groups of peaks. The first has ionization energy...
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Treating the sigma bonds in boron trifluoride, BF3 as vectors, the following reducible representation were
D3h
E
2C3
3C2
on
253
30 v
Tred
3
1
3
To what symmetry representation labels does this reduces to?
D
E
2C3
3C2
253
30,
* + y°. z?
A,'
1
1
A2'
1
-1
1
1
-1
R.
E'
2
(х, у)
(x² – y², xy)
A,"
1
1
-1
-1
A,"
1
1
-1
-1
-1
(R, R,)
(xz, yz)
E"
-1
-2
1
O 2'+E'
O 2A1'+ A2'
A1" + E"
O A1'+ E'
O Aj' +E"
2.
Transcribed Image Text:Treating the sigma bonds in boron trifluoride, BF3 as vectors, the following reducible representation were D3h E 2C3 3C2 on 253 30 v Tred 3 1 3 To what symmetry representation labels does this reduces to? D E 2C3 3C2 253 30, * + y°. z? A,' 1 1 A2' 1 -1 1 1 -1 R. E' 2 (х, у) (x² – y², xy) A," 1 1 -1 -1 A," 1 1 -1 -1 -1 (R, R,) (xz, yz) E" -1 -2 1 O 2'+E' O 2A1'+ A2' A1" + E" O A1'+ E' O Aj' +E" 2.
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Publisher:
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