1. Consider the molecule, iodine pentafluoride, IF5 a) What is the point group of IF5? b) Find a reducible representation covering all translational, rotational, and vibrational modes of IF5. (Hint: Your character for the identity should be 18) c) Reduce this representation into the irreducible components and use a character table to divide the irreducible representations up into rotational, translational, and vibrational symmetries. d) Which vibrational modes will be IR active?
1. Consider the molecule, iodine pentafluoride, IF5 a) What is the point group of IF5? b) Find a reducible representation covering all translational, rotational, and vibrational modes of IF5. (Hint: Your character for the identity should be 18) c) Reduce this representation into the irreducible components and use a character table to divide the irreducible representations up into rotational, translational, and vibrational symmetries. d) Which vibrational modes will be IR active?
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.29E: Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal...
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