2) Consider the character table for ammonia (C3v). E 2C3 (2) 30v linear, rotations quadratic A₁ 1 1 1 Z x²+y², z² A₂ 1 1 -1 Rz E 2 0 (x, y) (Rx, Ry) (x²-y², xy) (xz, yz) The total reducible representation is: tot 3A1+1A2 + 8E a) How many vibrations are expected for ammonia?
2) Consider the character table for ammonia (C3v). E 2C3 (2) 30v linear, rotations quadratic A₁ 1 1 1 Z x²+y², z² A₂ 1 1 -1 Rz E 2 0 (x, y) (Rx, Ry) (x²-y², xy) (xz, yz) The total reducible representation is: tot 3A1+1A2 + 8E a) How many vibrations are expected for ammonia?
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.12E
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Question
![2) Consider the character table for ammonia (C3v).
E
2C3 (2)
30v
linear,
rotations
quadratic
A₁
1
1
1
Z
x²+y², z²
Az
1
1
-1
E
2
Rz
0
(x, y) (Rx, Ry)
(x²-y², xy) (xz, yz)
The total reducible representation is:
Пtot
3A1+1A2 + 8E
a) How many vibrations are expected for ammonia?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc6ff5517-0a4b-49b9-b09c-f99c74e730ba%2Fa2e52601-18e4-4524-b4d8-60ce2fdcda22%2Fogm601c_processed.png&w=3840&q=75)
Transcribed Image Text:2) Consider the character table for ammonia (C3v).
E
2C3 (2)
30v
linear,
rotations
quadratic
A₁
1
1
1
Z
x²+y², z²
Az
1
1
-1
E
2
Rz
0
(x, y) (Rx, Ry)
(x²-y², xy) (xz, yz)
The total reducible representation is:
Пtot
3A1+1A2 + 8E
a) How many vibrations are expected for ammonia?
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