g) In part c, you found the symmetry of some d orbitals on the central Cl atom. Computational and experimental work confirm that the d-orbitals are not important for the bonding description of ClF; or other main group molecules with so-called "expanded octets." Think about the requirements for significant interaction we discussed in class and give a brief reason why d-orbital involvement is unlikely. (Hint: You should be able to offer a reasonable explanation without looking up any numbers or doing any calculations.)
g) In part c, you found the symmetry of some d orbitals on the central Cl atom. Computational and experimental work confirm that the d-orbitals are not important for the bonding description of ClF; or other main group molecules with so-called "expanded octets." Think about the requirements for significant interaction we discussed in class and give a brief reason why d-orbital involvement is unlikely. (Hint: You should be able to offer a reasonable explanation without looking up any numbers or doing any calculations.)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:g) In part c, you found the symmetry of some d orbitals on the central Cl atom.
Computational and experimental work confirm that the d-orbitals are not
important for the bonding description of CIF; or other main group molecules
with so-called "expanded octets." Think about the requirements for significant
interaction we discussed in class and give a brief reason why d-orbital
involvement is unlikely. (Hint: You should be able to offer a reasonable
explanation without looking up any numbers or doing any calculations.)
Transcribed Image Text:1) The molecule CIF; belongs to the point group shown below:
C4v
E 2C4
4
C2 20,
20d
A1
1
1
1
1
1
A2
1
1
-1
-1
B1
1
-1
1
1
-1
B2
1
-1
1
-1
1
E
0 -2
0 (x, y)
2
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