The van Deemter equation decribes how the column, stationary phase, and linear velocity influence plate height. The equation is HA+ + Cux B Ux Match each symbol with its term in the van Deemter equation. 1000 plate height linear velocity multiple path (eddy diffusion) equilibration time (mass transfer) longitudinal diffusion A B Answer Bank H Ux For an open tubular column (not capillary electrophoresis), which term(s) in the van Deemter equation does(do) not affect the plate height? O multiple paths

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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### Understanding the Van Deemter Equation

The Van Deemter equation describes how the column, stationary phase, and linear velocity influence plate height in chromatography. The equation is:

\[ H \approx A + \frac{B}{u_x} + C u_x \]

**Match each symbol with its term in the Van Deemter equation:**

1. **Plate Height:**
   - **Symbol:** \( H \)
   
2. **Linear Velocity:**
   - **Symbol:** \( u_x \)
   
3. **Multiple Path (Eddy Diffusion):**
   - **Symbol:** \( A \)
   
4. **Equilibration Time (Mass Transfer):**
   - **Symbol:** \( C \)
   
5. **Longitudinal Diffusion:**
   - **Symbol:** \( B \)

**Answer Bank:**
- \( A \)
- \( B \)
- \( C \)
- \( u_x \)
- \( H \)

**Question:**
For an open tubular column (not capillary electrophoresis), which term(s) in the Van Deemter equation does not affect the plate height?

- Multiple paths
Transcribed Image Text:### Understanding the Van Deemter Equation The Van Deemter equation describes how the column, stationary phase, and linear velocity influence plate height in chromatography. The equation is: \[ H \approx A + \frac{B}{u_x} + C u_x \] **Match each symbol with its term in the Van Deemter equation:** 1. **Plate Height:** - **Symbol:** \( H \) 2. **Linear Velocity:** - **Symbol:** \( u_x \) 3. **Multiple Path (Eddy Diffusion):** - **Symbol:** \( A \) 4. **Equilibration Time (Mass Transfer):** - **Symbol:** \( C \) 5. **Longitudinal Diffusion:** - **Symbol:** \( B \) **Answer Bank:** - \( A \) - \( B \) - \( C \) - \( u_x \) - \( H \) **Question:** For an open tubular column (not capillary electrophoresis), which term(s) in the Van Deemter equation does not affect the plate height? - Multiple paths
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