1.19. A gas is confined in a 0.47 m diameter cylinder by a piston, on which rests a weight. The mass of the piston and weight together is 150 kg. The local acceleration of gravity is 9.813 m-s-2, and atmospheric pressure is 101.57 kPa. (a) What is the force in newtons exerted on the gas by the atmosphere, the piston, and the weight, assuming no friction between the piston and cylinder? (b) What is the pressure of the gas in kPa? (c) If the gas in the cylinder is heated, it expands, pushing the piston and weight upward. If the piston and weight are raised 0.83 m, what is the work done by the gas in kJ? What is the change in potential energy of the piston and weight?

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A: Volume = 0.02 m3  Pressure = 1 × 105 Nm-2 Temperature = 27°C = 27 + 273 = 300 K  Total mass of gases…

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A: Given: Temperature = 298 K moles of CO2 = 3 moles a = 3.5924 L2.atm/mol2 b = 0.04267 L/mol

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A: 1) As per the given data we haveP1=1.88atm                      P2=0.958atmT1=42.10C(315.25K)…

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Kinetic-Theory of Gases

Kinetic theory of gases is the model or method which was developed in the 19th century by Maxwell and Boltzmann. This is possible as the interatomic force which is of short-range forces that are important for solids and liquids can be neglected for gases. This theory or gas law gives a molecular interpretation of the pressure and temperature of a gas and is consistent with gas laws and Avogadro’s hypothesis. This theory is very helpful to correctly explain the specific heat capacities of many gases, kinetic energy and it also explains the transport qualities such as viscosity, thermal conductivity, and diffusion with molecular parameters. As stated in the kinetic-molecular theory, the temperature of a substance or gas particle is related to the average kinetic energy of the particles of that substance. When a substance is heated, some of the absorbed energy is stored within the particles, while some of the energy increases the motion of the particles, called average kinetic energy.