Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 10.8, Problem 2.3ACP
To stay aloft, a blimp must achieve neutral buoyancy; that is, its density must equal that of the surrounding air. The density of the blimp is its total weight (blimp, helium and air, passengers, and ballast) divided by its volume. Assume that the gross weight of the blimp includes the blimp’s structure and the helium, but does not include the air in the ballonets or the weights of the passengers and ballast. If the ballonets are filled with 12,000 ft3 (340 m3) of air at 1.00 atm and 25 °C, what additional weight (of passengers and ballast) is required for neutral buoyancy?
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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
A chemistry graduate student is studying the rate of this reaction:
2 HI (g) →H2(g) +12(g)
She fills a reaction vessel with HI and measures its concentration as the reaction proceeds:
time
(minutes)
[IH]
0
0.800M
1.0
0.301 M
2.0
0.185 M
3.0
0.134M
4.0
0.105 M
Use this data to answer the following questions.
Write the rate law for this reaction.
rate
= 0
Calculate the value of the rate constant k.
k =
Round your answer to 2 significant digits. Also be
sure your answer has the correct unit symbol.
Chapter 10 Solutions
Chemistry & Chemical Reactivity
Ch. 10.1 - At the summit of Mount Everest (altitude = 8848...Ch. 10.2 - A large balloon contains 65.0 L of helium gas at...Ch. 10.2 - Prob. 10.3CYUCh. 10.2 - You have a 22-L cylinder of helium at a pressure...Ch. 10.2 - Prob. 10.5CYUCh. 10.3 - Prob. 10.6CYUCh. 10.3 - At 1.00 atm and 25 C, the density of dry air is...Ch. 10.3 - A 0.105-g sample of a gaseous compound has a...Ch. 10.4 - Prob. 10.9CYUCh. 10.5 - The halothane-oxygen mixture described in this...
Ch. 10.6 - Prob. 10.11CYUCh. 10.7 - Prob. 10.12CYUCh. 10.8 - Prob. 1.1ACPCh. 10.8 - Prob. 1.2ACPCh. 10.8 - At sea level, atmospheric pressure is 1.00 atm....Ch. 10.8 - Prob. 2.2ACPCh. 10.8 - To stay aloft, a blimp must achieve neutral...Ch. 10.8 - Nitrogen gas is produced not only by NaN3...Ch. 10.8 - Prob. 3.2ACPCh. 10 - Pressure (See Section 10.1 and Example 10.1.) The...Ch. 10 - The average barometric pressure at an altitude of...Ch. 10 - Indicate which represents the higher pressure in...Ch. 10 - Put the following in order of increasing pressure:...Ch. 10 - Prob. 5PSCh. 10 - Prob. 6PSCh. 10 - You have 3.5 L of NO at a temperature of 22.0 C....Ch. 10 - Prob. 8PSCh. 10 - Prob. 9PSCh. 10 - You have a sample of CO2 in flask A with a volume...Ch. 10 - You have a sample of gas in a flask with a volume...Ch. 10 - A sample of gas occupies 135 mL at 22.5 C; the...Ch. 10 - One of the cylinders of an automobile engine has a...Ch. 10 - A helium-filled balloon of the type used in...Ch. 10 - Nitrogen monoxide reacts with oxygen to give...Ch. 10 - Ethane bums in air to give H2O and CO2. 2 C2H6(g)...Ch. 10 - A 1.25-g sample of CO2 is contained in a 750.-mL...Ch. 10 - A balloon holds 30.0 kg of helium. What is the...Ch. 10 - A flask is first evacuated so that it contains no...Ch. 10 - Prob. 20PSCh. 10 - Prob. 21PSCh. 10 - Prob. 22PSCh. 10 - Forty miles above Earths surface, the temperature...Ch. 10 - Prob. 24PSCh. 10 - A gaseous organofluorine compound has a density of...Ch. 10 - Prob. 26PSCh. 10 - A 1 007-g sample of an unknown gas exerts a...Ch. 10 - A 0.0130-g sample of a gas with an empirical...Ch. 10 - A new boron hydride, BxHy, has been isolated. To...Ch. 10 - Acetaldehyde is a common liquid compound that...Ch. 10 - Iron reacts with hydrochloric acid to produce...Ch. 10 - Silane, SiH4, reacts with O2 to give silicon...Ch. 10 - Prob. 33PSCh. 10 - The hydrocarbon octane (C8H18) bums to give CO2...Ch. 10 - Prob. 35PSCh. 10 - A self-contained underwater breathing apparatus...Ch. 10 - What is the total pressure in atmospheres of a gas...Ch. 10 - A cylinder of compressed gas is labeled...Ch. 10 - A halothane-oxygen mixture (C2HBrCIF3 + O2) can be...Ch. 10 - A collapsed balloon is filled with He to a volume...Ch. 10 - You have two flasks of equal volume. Flask A...Ch. 10 - Equal masses of gaseous N2 and Ar are placed in...Ch. 10 - If the rms speed of an oxygen molecule is 4.28 ...Ch. 10 - Prob. 44PSCh. 10 - Place the following gases in order of increasing...Ch. 10 - Prob. 46PSCh. 10 - In each pair of gases below, tell which will...Ch. 10 - Prob. 48PSCh. 10 - Prob. 49PSCh. 10 - A sample of uranium fluoride is found to effuse at...Ch. 10 - Prob. 51PSCh. 10 - Prob. 52PSCh. 10 - In the text, it is stated that the pressure of...Ch. 10 - You want to store 165 g of CO2 gas in a 12.5-L...Ch. 10 - Consider a 5.00-L tank containing 325 g of H2O at...Ch. 10 - Consider a 5.00-L tank containing 375 g of Ar at a...Ch. 10 - Complete the following table:Ch. 10 - On combustion, 1.0 L of a gaseous compound of...Ch. 10 - You have a sample of helium gas at 33 C, and you...Ch. 10 - Prob. 60GQCh. 10 - Butyl mercaptan, C4H9SH, has a very bad odor and...Ch. 10 - Prob. 62GQCh. 10 - The temperature of the atmosphere on Mars can be...Ch. 10 - If you place 2.25 g of solid silicon in a 6.56-L...Ch. 10 - What volume (in liters) of O2, measured at...Ch. 10 - Nitroglycerin decomposes into four different gases...Ch. 10 - Ni(CO)4 can be made by reacting finely divided...Ch. 10 - Ethane bums in air to give H2O and CO2. 2 C2H6(g)...Ch. 10 - You have four gas samples: 1. 1.0 L of H2 at STP...Ch. 10 - Propane reacts with oxygen to give carbon dioxide...Ch. 10 - Iron carbonyl can be made by the direct reaction...Ch. 10 - Prob. 72GQCh. 10 - There are five compounds in the family of...Ch. 10 - A miniature volcano can be made in the laboratory...Ch. 10 - The density of air 20 km above Earths surface is...Ch. 10 - Prob. 76GQCh. 10 - Chlorine dioxide, ClO2, reacts with fluorine to...Ch. 10 - A xenon fluoride can be prepared by heating a...Ch. 10 - Prob. 79GQCh. 10 - Prob. 80GQCh. 10 - Prob. 81GQCh. 10 - Carbon dioxide, CO2, was shown lo effuse through a...Ch. 10 - Prob. 84GQCh. 10 - Prob. 85GQCh. 10 - Prob. 86GQCh. 10 - You are given 1.56 g of a mixture of KClO3 and...Ch. 10 - A study of climbers who reached the summit of...Ch. 10 - Nitrogen monoxide reacts with oxygen to give...Ch. 10 - Ammonia gas is synthesized by combining hydrogen...Ch. 10 - Nitrogen trifluoride is prepared by the reaction...Ch. 10 - Chlorine trifluoride, ClF3, is a valuable reagent...Ch. 10 - Prob. 93GQCh. 10 - Prob. 94GQCh. 10 - You have a 550.-mL tank of gas with a pressure of...Ch. 10 - Prob. 96ILCh. 10 - Prob. 97ILCh. 10 - Group 2A metal carbonates are decomposed to the...Ch. 10 - One way to synthesize diborane, B2H6, is the...Ch. 10 - You are given a solid mixture of NaNO2 and NaCl...Ch. 10 - You have 1.249 g of a mixture of NaHCO3 and...Ch. 10 - Prob. 102ILCh. 10 - Many nitrate salts can be decomposed by heating....Ch. 10 - You have a gas, one of the three known...Ch. 10 - Prob. 106ILCh. 10 - A 1.0-L flask contains 10.0 g each of O2 and CO2...Ch. 10 - If equal masses of O2 and N2 are placed in...Ch. 10 - You have two pressure-proof steel cylinders of...Ch. 10 - Prob. 110SCQCh. 10 - Prob. 111SCQCh. 10 - Each of four flasks is filled with a different...Ch. 10 - Prob. 113SCQCh. 10 - The sodium azide required for automobile air bags...Ch. 10 - Prob. 115SCQCh. 10 - Prob. 116SCQ
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