(a) Use the following data for NH3 (g) at T = 273 K to evaluate B2P (T). (Here Z is thecompressibility factor, PV/RT).P (bar)0.100.200.300.400.500.600.70Note: You will need to fit this data to a least-squares line.(b) At standard temperature (273.15 K), the density of O₂ varies with pressure as indicated inthe table below:P (bar)0.253310.506630.759941.01325Z-11.519 x 10-43.038 x 10-44.557x 10-46.071 x 10-47.583 x 10-49.002 x 10-41.0551 x 10-32p(g/L)0.3569850.7141541.0714851.428962Use this data to find the second virial coefficient, B2v, of oxygen. Note that mo2 = 31.9988Daltons. (Hint: It will be useful to determine the molar volume from each value of p.)

Answered: Image /qna-images/answer/924511a0-7b9a-4ed1-bc28-9a416e5a4410.jpg

(a) Use the following data for NH3 (g) at T = 273 K to evaluate B2P (T). (Here Z is the compressibility factor, PV/RT). P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 0.70 P (bar) 0.25331 0.50663 0.75994 1.01325 Z-1 1.519 x 10-4 2 3.038 x 10-4 4.557x 10-4 Note: You will need to fit this data to a least-squares line. (b) At standard temperature (273.15 K), the density of O₂ varies with pressure as indicate the table below: 6.071 x 10-4 7.583 x 10-4 9.002 x 10-4 1.0551 x 10-3 p(g/L) 0.356985 0.714154 1.071485 1.428962 Use this data to find the second virial coefficient, B2v, of oxygen. Note that mo2 = 31.9988 Daltons. (Hint: It will be useful to determine the molar volume from each value of p.)

(a) Use the following data for NH3 (g) at T = 273 K to evaluate B2P (T). (Here Z is the compressibility factor, PV/RT). P (bar) 0.10 0.20 0.30 0.40 0.50 0.60 0.70 P (bar) 0.25331 0.50663 0.75994 1.01325 Z-1 1.519 x 10-4 2 3.038 x 10-4 4.557x 10-4 Note: You will need to fit this data to a least-squares line. (b) At standard temperature (273.15 K), the density of O₂ varies with pressure as indicate the table below: 6.071 x 10-4 7.583 x 10-4 9.002 x 10-4 1.0551 x 10-3 p(g/L) 0.356985 0.714154 1.071485 1.428962 Use this data to find the second virial coefficient, B2v, of oxygen. Note that mo2 = 31.9988 Daltons. (Hint: It will be useful to determine the molar volume from each value of p.)

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter16: Spontaneity Of Reaction

Section: Chapter Questions

Problem 85QAP: Which of the following quantities can be taken to be independent of temperature? independent of...

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