The virial equation of state may also be written as an expansion in terms of pressure: Z = 1 + B'p + ... The critical constants for water, H2O, are 218.3 atm. 55.3 cm3 mol-1 and 647.4 K. Assuming that the expansion may be truncated after the second term, calculate the value of the second virial coefficientB' at the critical temperature.
The virial equation of state may also be written as an expansion in terms of pressure: Z = 1 + B'p + ... The critical constants for water, H2O, are 218.3 atm. 55.3 cm3 mol-1 and 647.4 K. Assuming that the expansion may be truncated after the second term, calculate the value of the second virial coefficientB' at the critical temperature.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter1: Gases And The Zeroth Law Of Thermodynamics
Section: Chapter Questions
Problem 1.65E: Determine an expression for V/T p, n in terms of and . Does the sign on the expression make sense...
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The virial equation of state may also be written as an expansion in terms of pressure: Z = 1 + B'p + ... The critical constants for water, H2O, are 218.3 atm. 55.3 cm3 mol-1 and 647.4 K. Assuming that the expansion may be truncated after the second term, calculate the value of the second virial coefficient
B' at the critical temperature.
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