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13. (a) Calculate the pressure of Xe gas using the ideal gas law and the van der Waals equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly at a temperature of 500°C and a molar volume of 0.200 L mol-¹ (Note: for Xe a = 4.192 dmº bar mol-² and b = 0.0516 dm³ mol-¹) ]For each set of conditions in part (a), calculate the % deviation from the ideal (b) pressure. (c) [ intermolecular Explain the deviation from ideality for each set of conditions in terms of forces, temperature, and the effect of the size of the Xe atoms as appropriate.

13. (a) Calculate the pressure of Xe gas using the ideal gas law and the van der Waals equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly at a temperature of 500°C and a molar volume of 0.200 L mol-¹ (Note: for Xe a = 4.192 dmº bar mol-² and b = 0.0516 dm³ mol-¹) ]For each set of conditions in part (a), calculate the % deviation from the ideal (b) pressure. (c) [ intermolecular Explain the deviation from ideality for each set of conditions in terms of forces, temperature, and the effect of the size of the Xe atoms as appropriate.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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13. (a) - Calculate the pressure of Xe gas using the ideal gas law and the van der Waals equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly at a temperature of 500°C and a molar volume of 0.200 L mol-¹ (Note: for Xe a = 4.192 dmº bar mol-2 and b = 0.0516 dm³ mol-¹) ]For each set of conditions in part (a), calculate the % deviation from the ideal (b) pressure. 1 (c) [ intermolecular Explain the deviation from ideality for each set of conditions in terms of forces, temperature, and the effect of the size of the Xe atoms as appropriate.
Transcribed Image Text:13. (a) - Calculate the pressure of Xe gas using the ideal gas law and the van der Waals equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly at a temperature of 500°C and a molar volume of 0.200 L mol-¹ (Note: for Xe a = 4.192 dmº bar mol-2 and b = 0.0516 dm³ mol-¹) ]For each set of conditions in part (a), calculate the % deviation from the ideal (b) pressure. 1 (c) [ intermolecular Explain the deviation from ideality for each set of conditions in terms of forces, temperature, and the effect of the size of the Xe atoms as appropriate.
Expert Solution
Step 1: Ideal gas and real gas
  • The gases which follow the ideal gas law are called ideal gases.
  • The gases which follow the van der Waals equation of state are called real gases.
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