The gas-phase reaction between methanol (A) and acetic acid (B) to form methyl acetate (C) and water (D) CH3OH + CH3COOH=CH300CCH3 + H2O takes place in a batch reactor and proceeds to equilibrium. When the reactor mixture comes to equilibrium, the mole fractions of the four reactive species are related by a reaction equilibrium constant Ус Ур = Keg = 5.87 Ул Ув The feed to the reactor consists of nAo, NBo, nco, Npo and njo gram moles of A, B, C, D and an inert gas I respectively. a. If nao = 0.600 ngo, and all other input quantities are 0.0, what is the equilibrium fractional conversion of A? i 0.8945 b. It is desired to produce 65.0 moles of methyl acetate starting with 70.0 moles of methanol, an unknown amount of acetic acid, and no other components. If the reaction proceeds to equilibrium, how much acetic acid must be fed? Required acetic acid: 208.95 mol

Introduction to Chemical Engineering Thermodynamics
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ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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The gas-phase reaction between methanol (A) and acetic acid (B) to form methyl acetate (C) and water (D)
CH3OH + CH3COOH= CH300CCH3 + H2O
takes place in a batch reactor and proceeds to equilibrium. When the reactor mixture comes to equilibrium, the mole fractions of the
four reactive species are related by a reaction equilibrium constant
УС УD
Keq
= 5.87
УА Ув
The feed to the reactor consists of nAo, NBO, Nco, NDo and njo gram moles of A, B, C, D and an inert gas I respectively.
a. If nao = 0.600 ngo, and all other input quantities are 0.0, what is the equilibrium fractional conversion of A?
i
0.8945
b. It is desired to produce 65.0 moles of methyl acetate starting with 70.0 moles of methanol, an unknown amount of acetic acid, and
no other components.
If the reaction proceeds to equilibrium, how much acetic acid must be fed?
Required acetic acid:
208.95
mol
Transcribed Image Text:The gas-phase reaction between methanol (A) and acetic acid (B) to form methyl acetate (C) and water (D) CH3OH + CH3COOH= CH300CCH3 + H2O takes place in a batch reactor and proceeds to equilibrium. When the reactor mixture comes to equilibrium, the mole fractions of the four reactive species are related by a reaction equilibrium constant УС УD Keq = 5.87 УА Ув The feed to the reactor consists of nAo, NBO, Nco, NDo and njo gram moles of A, B, C, D and an inert gas I respectively. a. If nao = 0.600 ngo, and all other input quantities are 0.0, what is the equilibrium fractional conversion of A? i 0.8945 b. It is desired to produce 65.0 moles of methyl acetate starting with 70.0 moles of methanol, an unknown amount of acetic acid, and no other components. If the reaction proceeds to equilibrium, how much acetic acid must be fed? Required acetic acid: 208.95 mol
What is the composition of the final product?
Yacetic acid:
0.516
Ymethylacetate:
i
0.0179
Ymethanol:
0.233
Ywater:
0.233
c. Suppose it were important to reduce the concentration of methanol by making its conversion at equilibrium 98.5%. Again,
assuming the feed to the reactor contains only methanol and acetic acid and that it is desired to produce 65.0 moles of methyl
acetate, determine the extent of reaction and moles of methanol and acetic acid that must be fed to the reactor.
Extent:
65
Required methanol:
65.98
mol
Required acetic acid:
i
1459.5
mol
Transcribed Image Text:What is the composition of the final product? Yacetic acid: 0.516 Ymethylacetate: i 0.0179 Ymethanol: 0.233 Ywater: 0.233 c. Suppose it were important to reduce the concentration of methanol by making its conversion at equilibrium 98.5%. Again, assuming the feed to the reactor contains only methanol and acetic acid and that it is desired to produce 65.0 moles of methyl acetate, determine the extent of reaction and moles of methanol and acetic acid that must be fed to the reactor. Extent: 65 Required methanol: 65.98 mol Required acetic acid: i 1459.5 mol
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