The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia. C6H4ClNO2 + 2NH3 → O2NC6H4NH2 + NH4Cl This liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m3/kmol•min at 188 oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m3 and 6.6 kmol/m3, respectively. Gas constant: R = 1.987 cal/(K∙mol). (c) Write –rA solely as a function of conversion. (d) What is the initial rate of reaction (X = 0) at 188 oC? (e) What is the initial rate of reaction (X = 0) at 25 oC?
The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia. C6H4ClNO2 + 2NH3 → O2NC6H4NH2 + NH4Cl This liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m3/kmol•min at 188 oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m3 and 6.6 kmol/m3, respectively. Gas constant: R = 1.987 cal/(K∙mol). (c) Write –rA solely as a function of conversion. (d) What is the initial rate of reaction (X = 0) at 188 oC? (e) What is the initial rate of reaction (X = 0) at 25 oC?
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The formation of orthonitroaniline is from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia.
C6H4ClNO2 + 2NH3 → O2NC6H4NH2 + NH4Cl
This liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m3/kmol•min at 188 oC with E = 11273 cal/mol. The initial entering concentration of ONCB and ammonia are 1.8 kmol/m3 and 6.6 kmol/m3, respectively. Gas constant: R = 1.987 cal/(K∙mol).
(c) Write –rA solely as a function of conversion.
(d) What is the initial rate of reaction (X = 0) at 188 oC?
(e) What is the initial rate of reaction (X = 0) at 25 oC?
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