Table Q4 shows the solubility of liquid trichlorohexane in toluene (also liquid) at equilibrium at different temperatures, where species 1 is trichlorohexane and species 2 is toluene. These data are obtained at 1 atm. X1 0.037 0.050 0.085 0.135 0.199 0.288 0.364 0.482 Temperature (°C) 92.18 100.00 107.11 111.96 113.84 112.87 109.63 101.91 100.00 90.05 (a) Plot a properly labeled T-x₁ diagram of this binary mixture at 1 atm. (b) Estimate the composition of each phase at 110°C for this binary mixture. Table Q4 0.500 0.585 (c) At 110°C and 1 atm, trichlorohexane is added dropwise into an initially pure toluene until the mole fraction of trichlorohexane reaches 0.5. Assuming equilibrium is preserved during every addition of trichlorohexane, describe what you would see if the whole process is conducted in a transparent beaker. (d) At 100°C, determine the A12 and A21 in the two-constant Margules equation. Justify any assumptions that you make.
Table Q4 shows the solubility of liquid trichlorohexane in toluene (also liquid) at equilibrium at different temperatures, where species 1 is trichlorohexane and species 2 is toluene. These data are obtained at 1 atm. X1 0.037 0.050 0.085 0.135 0.199 0.288 0.364 0.482 Temperature (°C) 92.18 100.00 107.11 111.96 113.84 112.87 109.63 101.91 100.00 90.05 (a) Plot a properly labeled T-x₁ diagram of this binary mixture at 1 atm. (b) Estimate the composition of each phase at 110°C for this binary mixture. Table Q4 0.500 0.585 (c) At 110°C and 1 atm, trichlorohexane is added dropwise into an initially pure toluene until the mole fraction of trichlorohexane reaches 0.5. Assuming equilibrium is preserved during every addition of trichlorohexane, describe what you would see if the whole process is conducted in a transparent beaker. (d) At 100°C, determine the A12 and A21 in the two-constant Margules equation. Justify any assumptions that you make.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:Table Q4 shows the solubility of liquid trichlorohexane in toluene (also liquid) at equilibrium at
different temperatures, where species 1 is trichlorohexane and species 2 is toluene. These data are
obtained at 1 atm.
X1
0.037
0.050
0.085
0.135
0.199
0.288
0.364
0.482
0.500
0.585
Table Q4
Temperature (°C)
92.18
100.00
107.11
111.96
113.84
112.87
109.63
101.91
100.00
90.05
(a) Plot a properly labeled T-x₁ diagram of this binary mixture at 1 atm.
(b) Estimate the composition of each phase at 110°C for this binary mixture.
(c) At 110°C and 1 atm, trichlorohexane is added dropwise into an initially pure toluene until the
mole fraction of trichlorohexane reaches 0.5. Assuming equilibrium is preserved during every
addition of trichlorohexane, describe what you would see if the whole process is conducted in
a transparent beaker.
(d) At 100°C, determine the A12 and A21 in the two-constant Margules equation. Justify any
assumptions that you make.
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Step 1: Determine 1) labelled plot for T-x1 diagram 2) Composition of each phase 3) observations .
VIEWStep 2: Plot a labelled T-x1 diagram for the binary mixture.
VIEWStep 3: Calculate composition of each phase 110 degree Celsius.
VIEWStep 4: Determine changes observed when the whole process was conducted in a transparent beaker.
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