Determine the boiling point and vapor phase of a water-toluene mixture at atm (P = 760 mmHg), assuming the complete immiscibility of the components. The Antoine constants of the pure components (given for p0 [torr] and T [C0]) are given below. The graphical representation of the data needed is also provided. The boiling point read from the diagram is 87.78 0C. At this temperature value find the following: (a.) values of the vapor pressures of the liquids b.) mole fraction of water in the vapor phase according to Dalton's Law (c.) mole fraction of toluene in the vapor phase

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Determine the boiling point and vapor phase of a water-toluene mixture at atm (P = 760 mmHg), assuming the complete immiscibility of the components. The Antoine constants of the pure components (given for p0 [torr] and T [C0]) are given below. The graphical representation of the data needed is also provided.

The boiling point read from the diagram is 87.78 0C. At this temperature value find the following:
(a.) values of the vapor pressures of the liquids
b.) mole fraction of water in the vapor phase according to Dalton's Law
(c.) mole fraction of toluene in the vapor phase

  Water (liquid 1) Toluene (liquid 2)
B 1730.63 1644.050
A 8.07131 7.5596
C 233.426 233.524
800
700
760-p°1
600
500
400
300
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100
60
T[°C]
30
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70
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100
Determination of the boiling temperature at the atmospheric distillation of two immiscible
liquids.
P[torr]
Transcribed Image Text:800 700 760-p°1 600 500 400 300 200 100 60 T[°C] 30 40 50 70 80 90 100 Determination of the boiling temperature at the atmospheric distillation of two immiscible liquids. P[torr]
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