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1. An impure sample of compound A is contaminated with two impurities B and C. The sample is to be purified by recrystallization using ethanol as the solvent. The solubility properties of the three components are summarized below. Solubility in Solubility in ethanol Solubility in 50 mL Solubility in 50 mL ethanol at -78 °C at - 0°C ethanol at -78 °C ethanol at - 0°C (g) (g) Compound A 0.12 g/mL 0.02 g/mL Impurity B 0.58 g/mL 0.04 g/mL Impurity C 0.005 g/mL 0.0003 g/mL The impure (7.5 g) sample contains 5.0 g of compound A, 1.5 g of B and 1.0 g of C and is recrystallized using 50 mL of ethanol. The sample is boiled with 50 mL of ethanol, filtered by gravity and then cooled in ice and filtered by suction. a) How much compound A should be obtained as the final product? Will the sample be contaminated with any of the impurities? Explain (using calculations to support your answer-fill in the missing masses in the table above). Hint: For this question you should calculate the mass of each component present in the solid and solution phases at each step of the process. Fill in the missing data in the table above. How much of each component will dissolve in the hot solvent? How much of each component will be removed from the system during the hot gravity filtration? How much of each component will crystallize when cooled? How much of each component will be obtained as the solid portion during the suction filtration? You may write the answer in paragraph format or as a diagram, with some explanation.

1. An impure sample of compound A is contaminated with two impurities B and C. The sample is to be purified by recrystallization using ethanol as the solvent. The solubility properties of the three components are summarized below. Solubility in Solubility in ethanol Solubility in 50 mL Solubility in 50 mL ethanol at -78 °C at - 0°C ethanol at -78 °C ethanol at - 0°C (g) (g) Compound A 0.12 g/mL 0.02 g/mL Impurity B 0.58 g/mL 0.04 g/mL Impurity C 0.005 g/mL 0.0003 g/mL The impure (7.5 g) sample contains 5.0 g of compound A, 1.5 g of B and 1.0 g of C and is recrystallized using 50 mL of ethanol. The sample is boiled with 50 mL of ethanol, filtered by gravity and then cooled in ice and filtered by suction. a) How much compound A should be obtained as the final product? Will the sample be contaminated with any of the impurities? Explain (using calculations to support your answer-fill in the missing masses in the table above). Hint: For this question you should calculate the mass of each component present in the solid and solution phases at each step of the process. Fill in the missing data in the table above. How much of each component will dissolve in the hot solvent? How much of each component will be removed from the system during the hot gravity filtration? How much of each component will crystallize when cooled? How much of each component will be obtained as the solid portion during the suction filtration? You may write the answer in paragraph format or as a diagram, with some explanation.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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1. An impure sample of compound A is contaminated with two impurities B and C. The sample is to be purified by recrystallization using ethanol as the solvent. The solubility properties of the three components are summarized below. Solubility in Solubility in ethanol Solubility in 50 mL Solubility in 50 mL ethanol at -78 °C at - 0°C ethanol at -78 °C ethanol at - 0°C (g) (g) Compound A 0.12 g/mL 0.02 g/mL Impurity B 0.58 g/mL 0.04 g/mL Impurity C 0.005 g/mL 0.0003 g/mL The impure (7.5 g) sample contains 5.0 g of compound A, 1.5 g of B and 1.0 g of C and is recrystallized using 50 mL of ethanol. The sample is boiled with 50 mL of ethanol, filtered by gravity and then cooled in ice and filtered by suction. a) How much compound A should be obtained as the final product? Will the sample be contaminated with any of the impurities? Explain (using calculations to support your answer-fill in the missing masses in the table above). Hint: For this question you should calculate the mass of each component present in the solid and solution phases at each step of the process. Fill in the missing data in the table above. How much of each component will dissolve in the hot solvent? How much of each component will be removed from the system during the hot gravity filtration? How much of each component will crystallize when cooled? How much of each component will be obtained as the solid portion during the suction filtration? You may write the answer in paragraph format or as a diagram, with some explanation.
Transcribed Image Text:1. An impure sample of compound A is contaminated with two impurities B and C. The sample is to be purified by recrystallization using ethanol as the solvent. The solubility properties of the three components are summarized below. Solubility in Solubility in ethanol Solubility in 50 mL Solubility in 50 mL ethanol at -78 °C at - 0°C ethanol at -78 °C ethanol at - 0°C (g) (g) Compound A 0.12 g/mL 0.02 g/mL Impurity B 0.58 g/mL 0.04 g/mL Impurity C 0.005 g/mL 0.0003 g/mL The impure (7.5 g) sample contains 5.0 g of compound A, 1.5 g of B and 1.0 g of C and is recrystallized using 50 mL of ethanol. The sample is boiled with 50 mL of ethanol, filtered by gravity and then cooled in ice and filtered by suction. a) How much compound A should be obtained as the final product? Will the sample be contaminated with any of the impurities? Explain (using calculations to support your answer-fill in the missing masses in the table above). Hint: For this question you should calculate the mass of each component present in the solid and solution phases at each step of the process. Fill in the missing data in the table above. How much of each component will dissolve in the hot solvent? How much of each component will be removed from the system during the hot gravity filtration? How much of each component will crystallize when cooled? How much of each component will be obtained as the solid portion during the suction filtration? You may write the answer in paragraph format or as a diagram, with some explanation.
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