O Flash Distillation (or Single-Stage Contact) A mixture of 60 mole % n-heptane and 40 mole % toluene is vaporized at 101.325 kPa (absolute) until 40 moles of vapor and 60 moles of liquid in equilibrium with each other are produced. This occurs in a single- stage system and the vapor and liquid are kept in contact until equilibrium is achieved. Calculate the composition of the vapor and liquid. Note: Assume the system exhibits ideal behavior (which it mostly does), e.g. Raoult's Law applies and an Antoine's Vapor Pressure correlation is a sufficiently accurate model of component vapor pressure. Assume x 0.5 0.7 0.468 100 Feed Heptane 0.6 Toluene 0.4 Calcy Check Eq 0.75 0.865 0.45 0.798 1.313 0.798 1.04E-06 A 1.00 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 0.00 T, P Flash Hill Vapor Heptane Toluene Check Heptane Toluene Liquid Heptane Toluene 40 0.798 31.94 0.202 8.06 Feed 60.00 40.00 V+L 60.00 40.00 60 0.468 28.06 0.532 31.94 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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3) Flash Distillation (or Single-Stage Contact)
A mixture of 60 mole % n-heptane and 40 mole % toluene is vaporized at 101.325 kPa (absolute) until 40
moles of vapor and 60 moles of liquid in equilibrium with each other are produced. This occurs in a single-
stage system and the vapor and liquid are kept in contact until equilibrium is achieved. Calculate the
composition of the vapor and liquid.
Note: Assume the system exhibits ideal behavior (which it mostly does), e.g. Raoult's Law applies and an
Antoine's Vapor Pressure correlation is a sufficiently accurate model of component vapor pressure.
Assume x
0.5
0.7
0.468
Feed
Heptane 0.6
Toluene 0.4
100
Calcy Check Eq
0.75 0.865
0.45
1.313
0.798
0.798
1.04E-06
1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
T, P
Flash
Vapor
Heptane
Toluene
Check
Heptane
Toluene
Liquid
Heptane
Toluene
40
0.798
0.202
Feed
60.00
40.00
60
0.468
0.532
31.94
8.06
V+L
60.00
40.00
28.06
31.94
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
X
oulev aids o
BHA
Transcribed Image Text:3) Flash Distillation (or Single-Stage Contact) A mixture of 60 mole % n-heptane and 40 mole % toluene is vaporized at 101.325 kPa (absolute) until 40 moles of vapor and 60 moles of liquid in equilibrium with each other are produced. This occurs in a single- stage system and the vapor and liquid are kept in contact until equilibrium is achieved. Calculate the composition of the vapor and liquid. Note: Assume the system exhibits ideal behavior (which it mostly does), e.g. Raoult's Law applies and an Antoine's Vapor Pressure correlation is a sufficiently accurate model of component vapor pressure. Assume x 0.5 0.7 0.468 Feed Heptane 0.6 Toluene 0.4 100 Calcy Check Eq 0.75 0.865 0.45 1.313 0.798 0.798 1.04E-06 1.00 0.90 0.80 0.70 0.60 0.50 0.40 0.30 0.20 0.10 0.00 T, P Flash Vapor Heptane Toluene Check Heptane Toluene Liquid Heptane Toluene 40 0.798 0.202 Feed 60.00 40.00 60 0.468 0.532 31.94 8.06 V+L 60.00 40.00 28.06 31.94 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 X oulev aids o BHA
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