The equilibrium constant, K., for the following reaction is 9.52×10-² at 350 K. CH4 (g) + CC14 (g) =2 CH2C12 (g) Calculate the equilibrium concentrations of reactants and product when 0.277 moles of CH4 and 0.277 moles of CCl4 are introduced into a 1.00 L vessel at 350 K. [ CH4] [ CC4] [ CH,Cl, ] = M %3D M %3D M

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Problem 1.1P
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The equilibrium constant, \( K_c \), for the following reaction is \( 9.52 \times 10^{-2} \) at \( 350 \text{ K} \).

\[
\text{CH}_4 \, (g) + \text{CCl}_4 \, (g) \rightleftharpoons 2 \, \text{CH}_2\text{Cl}_2 \, (g)
\]

Calculate the equilibrium concentrations of reactants and product when \( 0.277 \) moles of \(\text{CH}_4\) and \( 0.277 \) moles of \(\text{CCl}_4\) are introduced into a \( 1.00 \, \text{L} \) vessel at \( 350 \text{ K} \).

\[
[\text{CH}_4] = \, \text{M}
\]

\[
[\text{CCl}_4] = \, \text{M}
\]

\[
[\text{CH}_2\text{Cl}_2] = \, \text{M}
\]
Transcribed Image Text:The equilibrium constant, \( K_c \), for the following reaction is \( 9.52 \times 10^{-2} \) at \( 350 \text{ K} \). \[ \text{CH}_4 \, (g) + \text{CCl}_4 \, (g) \rightleftharpoons 2 \, \text{CH}_2\text{Cl}_2 \, (g) \] Calculate the equilibrium concentrations of reactants and product when \( 0.277 \) moles of \(\text{CH}_4\) and \( 0.277 \) moles of \(\text{CCl}_4\) are introduced into a \( 1.00 \, \text{L} \) vessel at \( 350 \text{ K} \). \[ [\text{CH}_4] = \, \text{M} \] \[ [\text{CCl}_4] = \, \text{M} \] \[ [\text{CH}_2\text{Cl}_2] = \, \text{M} \]
Expert Solution
Step 1

The given reaction is

CH4(g)+CCl4(g)2CH2Cl2(g)

Equilibrium constant for the reaction is 9.52×10-2 at 350K

moles of CH4= 0.277

moles of CCl4=0.277

We're asked to calculate the equilibrium concentrations of reactants and products.

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