The equilibrium constant, K, for the following reaction is 1.54×10-2 at 506 K. PCl5 (g)  PCl3 (g) +  Cl2 (g) An equilibrium mixture of the three gases in a 18.2 L container at 506 K contains 0.222 M PCl5,   5.84×10-2 M PCl3 and 5.84×10-2 M Cl2. What will be the concentrations of the three gases once equilibrium has been reestablished, if the equilibrium mixture is compressed at constant temperature to a volume of 9.70 L?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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The equilibrium constant, K, for the following reaction is 1.54×10-2 at 506 K.

PCl5

      (g) 

PCl3

      (g) + 

Cl2

    (g)


An equilibrium mixture of the three gases in a 18.2 L container at 506 K contains 0.222 M PCl5,   5.84×10-2 M PCl3 and 5.84×10-2 M Cl2. What will be the concentrations of the three gases once equilibrium has been reestablished, if the equilibrium mixture is compressed at constant temperature to a volume of 9.70 L?

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