The decomposition of nitramide, O₂NNH,, in water has the chemical equation and rate law [O₂NNH₂] [H+] O₂NNH, (aq)- -N₂O(g) + H₂O(1) A proposed mechanism for this reaction is 1.0,NNH, (aq) = O,NNH(aq) + H+ (aq) (fast equilibrium) rate = k 2.0, NNH (aq) N₂O(g) + OH- (aq) (slow) 3. H(aq) + OH-(aq) H₂O(l) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? k₂ Answer Bank k_ k3 k

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The decomposition of nitramide, O₂NNH,, in water has the chemical equation and rate law
[O₂NNH₂]
[H+]
O₂NNH, (aq)- -N₂O(g) + H₂O(1)
A proposed mechanism for this reaction is
1.0,NNH, (aq) =
O,NNH(aq) + H+ (aq) (fast equilibrium)
rate = k
2.0, NNH (aq) N₂O(g) + OH- (aq) (slow)
3. H(aq) + OH-(aq) H₂O(l) (fast)
What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism?
k₂
Answer Bank
k_
k3
k
Transcribed Image Text:The decomposition of nitramide, O₂NNH,, in water has the chemical equation and rate law [O₂NNH₂] [H+] O₂NNH, (aq)- -N₂O(g) + H₂O(1) A proposed mechanism for this reaction is 1.0,NNH, (aq) = O,NNH(aq) + H+ (aq) (fast equilibrium) rate = k 2.0, NNH (aq) N₂O(g) + OH- (aq) (slow) 3. H(aq) + OH-(aq) H₂O(l) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? k₂ Answer Bank k_ k3 k
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