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nd rate law

nd rate law

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The decomposition of nitramide, O, NNH,, in water has the chemical equation and rate law [0,NNH,] [H*] О,NNH, (aq) — N,O(g) + H,О(1) rate = A proposed mechanism for this reaction is k1 1. O,NNH, (aq) = 0,NNH (aq) + H* (aq) (fast equilibrium) k-1 k2 2. O,NNH (aq) → N,0(g) + OH¯(aq) (slow) k3 3. H (аq) + ОН (аq) — Н,О() (fast) H,O(1) (fast) > What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? Answer Bank k = k1 k-1 k3 k2
Transcribed Image Text:The decomposition of nitramide, O, NNH,, in water has the chemical equation and rate law [0,NNH,] [H*] О,NNH, (aq) — N,O(g) + H,О(1) rate = A proposed mechanism for this reaction is k1 1. O,NNH, (aq) = 0,NNH (aq) + H* (aq) (fast equilibrium) k-1 k2 2. O,NNH (aq) → N,0(g) + OH¯(aq) (slow) k3 3. H (аq) + ОН (аq) — Н,О() (fast) H,O(1) (fast) > What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? Answer Bank k = k1 k-1 k3 k2
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