The binary system n-hexane (1)+ethanol (2) obeys to the modified Raoult's law with the following activity coefficients expressions: Iny, = 1.5 x Iny = 1.5 xf 1. Show whether or not this system exhibits an azeotrope at 50°C. In case the azeotrope exists, determine its pressure and composition.

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Problem 1
The binary system n-hexane (1)+ethanol (2) obeys to the modified Raoult's law with the following
activity coefficients expressions:
Iny = 1.5 x
Inyz = 1.5 x}
1. Show whether or not this system exhibits an azeotrope at 50°C. In case the azeotrope exists,
determine its pressure and composition.
2. Over what range of pressure can this system exist as two liquid-vapor phases at 50°C for an
overall composition z2 = 0.4?
Transcribed Image Text:Problem 1 The binary system n-hexane (1)+ethanol (2) obeys to the modified Raoult's law with the following activity coefficients expressions: Iny = 1.5 x Inyz = 1.5 x} 1. Show whether or not this system exhibits an azeotrope at 50°C. In case the azeotrope exists, determine its pressure and composition. 2. Over what range of pressure can this system exist as two liquid-vapor phases at 50°C for an overall composition z2 = 0.4?
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