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13.9. Explicitly derive Eqn. (13.37) by filling in the missing steps. As we did in Chapter 12, we take the limit x, yi1 to eliminate the standard and pure- phase chemical potentials by relating them to the saturation pressure. The final result is (T, P, {y}) (T, P) -y,Р%3D7(Т, Р, {x})x,РуаР (Т) (13.37) where (T, P) gives the fugacity coefficient for pure i. Just as before, there are C of these

13.9. Explicitly derive Eqn. (13.37) by filling in the missing steps. As we did in Chapter 12, we take the limit x, yi1 to eliminate the standard and pure- phase chemical potentials by relating them to the saturation pressure. The final result is (T, P, {y}) (T, P) -y,Р%3D7(Т, Р, {x})x,РуаР (Т) (13.37) where (T, P) gives the fugacity coefficient for pure i. Just as before, there are C of these

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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13.9. Explicitly derive Eqn. (13.37) by filling in the missing steps.
Transcribed Image Text:13.9. Explicitly derive Eqn. (13.37) by filling in the missing steps.
As we did in Chapter 12, we take the limit x, yi1 to eliminate the standard and pure- phase chemical potentials by relating them to the saturation pressure. The final result is (T, P, {y}) (T, P) -y,Р%3D7(Т, Р, {x})x,РуаР (Т) (13.37) where (T, P) gives the fugacity coefficient for pure i. Just as before, there are C of these
Transcribed Image Text:As we did in Chapter 12, we take the limit x, yi1 to eliminate the standard and pure- phase chemical potentials by relating them to the saturation pressure. The final result is (T, P, {y}) (T, P) -y,Р%3D7(Т, Р, {x})x,РуаР (Т) (13.37) where (T, P) gives the fugacity coefficient for pure i. Just as before, there are C of these
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