Consider an ionic compound, MX3, composed of generic metal M and generic gaseous halogen X.The enthalpy of formation of MX3 is Δ?∘f =−583 kJ/mol.The enthalpy of sublimation of M is Δ?sub =161 kJ/mol.The first, second, and third ionization energies of M are IE1=643 kJ/mol, IE2=1715 kJ/mol, and IE3=2623 kJ/mol.The electron affinity of X is Δ?EA =−329 kJ/mol. (Refer to the hint).The bond energy of X2 is BE =193 kJ/mol.Determine the lattice energy of MX3.

Given, The enthalpy of formation of MX3 is ∆Hf° =−583 kJ/mol The enthalpy of sublimation of M is…

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Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

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Consider an ionic compound, MX3, composed of generic metal M and generic gaseous halogen X.

The enthalpy of formation of MX3 is Δ?∘f =−583 kJ/mol.
The enthalpy of sublimation of M is Δ?sub =161 kJ/mol.
The first, second, and third ionization energies of M are IE1=643 kJ/mol, IE2=1715 kJ/mol, and IE3=2623 kJ/mol.
The electron affinity of X is Δ?EA =−329 kJ/mol. (Refer to the hint).
The bond energy of X2 is BE =193 kJ/mol.

Determine the lattice energy of MX3.

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