Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity of several liquids at 20°C and I bar25 for use in Problems 3.13 to 3.15, where ß and x may be assumed constant. Table 3.2: Volumetric Properties of Liquids at 20°C Specific Isothermal Volume Molecular Volume Compressibility K/10-5 bar! Expansivity B/10-3.°C- Formula Chemical Name VIL-kg- C2H,O2 CH;N CS2 CGH5CI C,H12 C4H100 C2H5OH C4H3O2 C3H10 CH;OH Acetic Acid 0.951 9.08 1.08 Aniline 0.976 4.53 0.81 Carbon Disulfide 0.792 0.904 1.285 1.401 9.38 1.12 Chlorobenzene 7.45 0.94 Cyclohexane Diethyl Ether Ethanol 11.3 1.15 18.65 1.65 1.265 11.19 1.40 1.35 Ethyl Acetate т-Xylene 1.110 11.32 1.157 8.46 0.99 Methanol 1.262 12.14 1.49 Tetrachloromethane 0.628 10.5 1.14 C;Hg CHCI; Toluene 1.154 8.96 1.05 Trichloromethane 0.672 9.96 1.21 3.13. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is heated from 15°C to 25°C at a constant pres- sure of I bar. 3.14. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant temperature of 20°C.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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ANSWER 3.14 FOR DIETHYL ETHER ONLY AND PROVIDE THE EQUATIONS AND DERIVATIONS. AGAIN 3.14 FOR DIETHYL ETHER
Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity
of several liquids at 20°C and I bar25 for use in Problems 3.13 to 3.15, where ß and x may be
assumed constant.
Table 3.2: Volumetric Properties of Liquids at 20°C
Specific
Volume
VIL-kg-
Isothermal
Volume
Molecular
Compressibility
K/10-5 bar!
Expansivity
B/10-3.°C-
Formula
Chemical Name
9.08
CH,O2
CH;N
CS2
CGH5CI
C,H12
C4H100
C2H5OH
Acetic Acid
0.951
1.08
Aniline
0.976
4.53
0.81
Carbon Disulfide
0.792
9.38
1.12
Chlorobenzene
0.904
7.45
0.94
Cyclohexane
Diethyl Ether
Ethanol
1.285
1.401
11.3
18.65
1.15
1.65
11.19
11.32
1.265
1.40
1.35
Ethyl Acetate
т-Хylene
1.110
8.46
C3H10
CH;OH
CI4
C;Hg
CHCI3
1.157
0.99
Methanol
1.262
12.14
1.49
Tetrachloromethane
0.628
10.5
1.14
Toluene
1.154
8.96
1.05
1.21
Trichloromethane
0.672
9.96
3.13. For one of the substances in Table 3.2, compute the change in volume and work done
when one kilogram of the substance is heated from 15°C to 25°C at a constant pres-
sure of 1 bar.
3.14. For one of the substances in Table 3.2, compute the change in volume and work done
when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant
temperature of 20°C.
Transcribed Image Text:Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity of several liquids at 20°C and I bar25 for use in Problems 3.13 to 3.15, where ß and x may be assumed constant. Table 3.2: Volumetric Properties of Liquids at 20°C Specific Volume VIL-kg- Isothermal Volume Molecular Compressibility K/10-5 bar! Expansivity B/10-3.°C- Formula Chemical Name 9.08 CH,O2 CH;N CS2 CGH5CI C,H12 C4H100 C2H5OH Acetic Acid 0.951 1.08 Aniline 0.976 4.53 0.81 Carbon Disulfide 0.792 9.38 1.12 Chlorobenzene 0.904 7.45 0.94 Cyclohexane Diethyl Ether Ethanol 1.285 1.401 11.3 18.65 1.15 1.65 11.19 11.32 1.265 1.40 1.35 Ethyl Acetate т-Хylene 1.110 8.46 C3H10 CH;OH CI4 C;Hg CHCI3 1.157 0.99 Methanol 1.262 12.14 1.49 Tetrachloromethane 0.628 10.5 1.14 Toluene 1.154 8.96 1.05 1.21 Trichloromethane 0.672 9.96 3.13. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is heated from 15°C to 25°C at a constant pres- sure of 1 bar. 3.14. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant temperature of 20°C.
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