Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity of several liquids at 20°C and I bar25 for use in Problems 3.13 to 3.15, where ß and x may be assumed constant. Table 3.2: Volumetric Properties of Liquids at 20°C Specific Isothermal Volume Molecular Volume Compressibility K/10-5 bar! Expansivity B/10-3.°C- Formula Chemical Name VIL-kg- C2H,O2 CH;N CS2 CGH5CI C,H12 C4H100 C2H5OH C4H3O2 C3H10 CH;OH Acetic Acid 0.951 9.08 1.08 Aniline 0.976 4.53 0.81 Carbon Disulfide 0.792 0.904 1.285 1.401 9.38 1.12 Chlorobenzene 7.45 0.94 Cyclohexane Diethyl Ether Ethanol 11.3 1.15 18.65 1.65 1.265 11.19 1.40 1.35 Ethyl Acetate т-Xylene 1.110 11.32 1.157 8.46 0.99 Methanol 1.262 12.14 1.49 Tetrachloromethane 0.628 10.5 1.14 C;Hg CHCI; Toluene 1.154 8.96 1.05 Trichloromethane 0.672 9.96 1.21 3.13. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is heated from 15°C to 25°C at a constant pres- sure of I bar. 3.14. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant temperature of 20°C.
Table 3.2 provides the specific volume, isothermal compressibility, and volume expansivity of several liquids at 20°C and I bar25 for use in Problems 3.13 to 3.15, where ß and x may be assumed constant. Table 3.2: Volumetric Properties of Liquids at 20°C Specific Isothermal Volume Molecular Volume Compressibility K/10-5 bar! Expansivity B/10-3.°C- Formula Chemical Name VIL-kg- C2H,O2 CH;N CS2 CGH5CI C,H12 C4H100 C2H5OH C4H3O2 C3H10 CH;OH Acetic Acid 0.951 9.08 1.08 Aniline 0.976 4.53 0.81 Carbon Disulfide 0.792 0.904 1.285 1.401 9.38 1.12 Chlorobenzene 7.45 0.94 Cyclohexane Diethyl Ether Ethanol 11.3 1.15 18.65 1.65 1.265 11.19 1.40 1.35 Ethyl Acetate т-Xylene 1.110 11.32 1.157 8.46 0.99 Methanol 1.262 12.14 1.49 Tetrachloromethane 0.628 10.5 1.14 C;Hg CHCI; Toluene 1.154 8.96 1.05 Trichloromethane 0.672 9.96 1.21 3.13. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is heated from 15°C to 25°C at a constant pres- sure of I bar. 3.14. For one of the substances in Table 3.2, compute the change in volume and work done when one kilogram of the substance is compressed from 1 bar to 100 bar at a constant temperature of 20°C.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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ANSWER 3.14 FOR DIETHYL ETHER ONLY AND PROVIDE THE EQUATIONS AND DERIVATIONS.
AGAIN 3.14 FOR DIETHYL ETHER
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