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Of the following binary liquid/vapor systems, which can be approximately modeled by Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful. (a) Benzene/toluene at 1(atm).

Of the following binary liquid/vapor systems, which can be approximately modeled by Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful. (a) Benzene/toluene at 1(atm).

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Of the following binary liquid/vapor systems, which can be approximately modeled by
Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful.
(a) Benzene/toluene at 1(atm).
(b) n-Hexane/n-heptane at 25 bar.
(c) Hydrogen/propane at 200 K.
(d) Iso-octane/n-octane at 100°C.
(e) Water/n-decane at 1 bar.

Molar z cm't TJK 3224 TK Pbar ma Cyckpentane Cycloherane Mathykyckopentane Mehykyckiheane 70.134 0.196 SILS 45.00 0273 258 0210 5536 3539 020 5328 37 8 0272 0235 572 2123 319. MA 131. 3450 2.004 30.40 021 hopylene -Buene ci-2Butene truna-2-Butene 42 56.08 56.0 INKA 2253 0.19 420.0 0205 435 6 0218 428.6 043 0.277 4243 0.273 41.00 0.275 2393 2769 274.0 231 354 2389 2204 1-Heene 020 S040 0194 417.9 0.190 425 2 31.40 025 4000 0225 4277 0.26 3363 56.08 bobutylene 13-Butadiene 21. 82.145 26.008 78114 92.141 106.167 0212 504 41.50 0272 6139 0271 489 0271 41.06 0.264 36.06 0.263 3561 Cyclobenene Acetylene Benene 0210 52 259. 316. 3532 3838 Toluene Eshylbeneeme Cumene Xylene Xylene Xylene Styrene Naphthalene Biphenyl Formaldelyde Acetaldehyde Mathyl aetate Eyl actte Acetone 000 6172 427. 120 194 106.167 106.167 036 631I 0310 60 036 617.1 32.09 0.264 37.34 0.263 3536 0.299 4256 4176 376 4123 106 67 104 152 12114 154211 0322 6162 02 6MO 748.4 0365 793 35.11 0.20 38.40 0.256 4051 0.2 38.50 0.295 379 352 41A 522 30.006 44.063 74.079 0282 40O 46.0 6590 0223 55.50 0.221 115. 254.1 240 029 0331 154. 47.50 0253 22K. 5233 NO 0.255 2 3502 0.307 SON2 47.01 0.233 41.30 0.249 20 267. 3294 3528 Methyl ettyl ketone Dieyl eher Methyl rutyl ether Methan 72.07 0323 5355 74123 021 6.7 3.40 0.260 150 026 .1 0.564 S126 340 0273 s0.0 0.224 3379 Ethanol 0645 513.9 0622 5368 0.994 563.1 6LAS 0240 S1.75 0254 4423 0.20 167. 3514 3704 1-Propanol 1-Butanol 60.06 74.123 219. 275.
Transcribed Image Text:Molar z cm't TJK 3224 TK Pbar ma Cyckpentane Cycloherane Mathykyckopentane Mehykyckiheane 70.134 0.196 SILS 45.00 0273 258 0210 5536 3539 020 5328 37 8 0272 0235 572 2123 319. MA 131. 3450 2.004 30.40 021 hopylene -Buene ci-2Butene truna-2-Butene 42 56.08 56.0 INKA 2253 0.19 420.0 0205 435 6 0218 428.6 043 0.277 4243 0.273 41.00 0.275 2393 2769 274.0 231 354 2389 2204 1-Heene 020 S040 0194 417.9 0.190 425 2 31.40 025 4000 0225 4277 0.26 3363 56.08 bobutylene 13-Butadiene 21. 82.145 26.008 78114 92.141 106.167 0212 504 41.50 0272 6139 0271 489 0271 41.06 0.264 36.06 0.263 3561 Cyclobenene Acetylene Benene 0210 52 259. 316. 3532 3838 Toluene Eshylbeneeme Cumene Xylene Xylene Xylene Styrene Naphthalene Biphenyl Formaldelyde Acetaldehyde Mathyl aetate Eyl actte Acetone 000 6172 427. 120 194 106.167 106.167 036 631I 0310 60 036 617.1 32.09 0.264 37.34 0.263 3536 0.299 4256 4176 376 4123 106 67 104 152 12114 154211 0322 6162 02 6MO 748.4 0365 793 35.11 0.20 38.40 0.256 4051 0.2 38.50 0.295 379 352 41A 522 30.006 44.063 74.079 0282 40O 46.0 6590 0223 55.50 0.221 115. 254.1 240 029 0331 154. 47.50 0253 22K. 5233 NO 0.255 2 3502 0.307 SON2 47.01 0.233 41.30 0.249 20 267. 3294 3528 Methyl ettyl ketone Dieyl eher Methyl rutyl ether Methan 72.07 0323 5355 74123 021 6.7 3.40 0.260 150 026 .1 0.564 S126 340 0273 s0.0 0.224 3379 Ethanol 0645 513.9 0622 5368 0.994 563.1 6LAS 0240 S1.75 0254 4423 0.20 167. 3514 3704 1-Propanol 1-Butanol 60.06 74.123 219. 275.
Eitylene ghyod Acetic acid 0.47 7197 0.467 920 77.00 026 S76 0211 1910 197 2917 4705 40.64 022 -lutyric acid lenoic acid Actonitrile Mellylamine Tahylamine Nitmethane .106 6157 122.123 41.053 0603 751.0 0338 S45.5 4301 344. 173. 14. 4.20 06 4830 0.184 7460 0321 5224 354 266 31.057 45.04 61.040 Carton terachloride 153822 456.2 56.20 007 63.10 0223 4560 0272 54.72 0293 60.0 0265 6680 0276 0348 S8.2 0.193 5564 200. 173. 26. 3744 0222 SM4 29. Dichlonomethane S4932 0.199 S100 3129 249 Mellyl chloride Eahyl chloride Chbenene Tetraflathane Arpon Krypton Xenon 0.153 4163 143. 0.190 52.0 0275 200 112558 0250 624 45.20 0.265 0327 3742 399s 000 1509 40.60 028 4898 0291 55.02 028 58.40 026 247.1 873 198.0 746 0.000 209.4 912 1198 131.30 0.000 297 52 1650 Helium 4 4.003 -090 2.28 0.02 13.13 0305 573 42 2016 -0216 33.19 Hydrogen Oyp Nitogen Ais Chlorine 64.1 204 31.9 30.43 0 734 902 773 28014 008 1262 400 0.29 .0 1322 0.069 417.2 892 3745 0.2 348 70.905 124. 77.10 05 3499 029 7383 0274 7900 0275 Carton mononide Caron dionide 93.4 940 44.010 614 0224 3042 Carton disulfide 160. 3194 Hydognde Sulfur dionide 34.O2 0.004 3735 TK4 0.29 122. 127. 64.065 Sulfur ionide 0.424 909 0583 I80.2 K.10 025 640 0251 3179 Nitric anide (NO) 000 1214 Nis aide N0) H013 Hydrogen chloride Hydropen yanide Water 0.141 2096 0132 3247 7245 0274 KA10 029 33.90 0.197 0345 647.1 2055 0229 974 21.026 IKOIS 139. 3732 297 Ammnia Nre d Sulfurk aid 17.031 0.3 105.7 I1230 0212 68.90 0231 61.00 0.7 725 145 177. 0714 S200 ...
Transcribed Image Text:Eitylene ghyod Acetic acid 0.47 7197 0.467 920 77.00 026 S76 0211 1910 197 2917 4705 40.64 022 -lutyric acid lenoic acid Actonitrile Mellylamine Tahylamine Nitmethane .106 6157 122.123 41.053 0603 751.0 0338 S45.5 4301 344. 173. 14. 4.20 06 4830 0.184 7460 0321 5224 354 266 31.057 45.04 61.040 Carton terachloride 153822 456.2 56.20 007 63.10 0223 4560 0272 54.72 0293 60.0 0265 6680 0276 0348 S8.2 0.193 5564 200. 173. 26. 3744 0222 SM4 29. Dichlonomethane S4932 0.199 S100 3129 249 Mellyl chloride Eahyl chloride Chbenene Tetraflathane Arpon Krypton Xenon 0.153 4163 143. 0.190 52.0 0275 200 112558 0250 624 45.20 0.265 0327 3742 399s 000 1509 40.60 028 4898 0291 55.02 028 58.40 026 247.1 873 198.0 746 0.000 209.4 912 1198 131.30 0.000 297 52 1650 Helium 4 4.003 -090 2.28 0.02 13.13 0305 573 42 2016 -0216 33.19 Hydrogen Oyp Nitogen Ais Chlorine 64.1 204 31.9 30.43 0 734 902 773 28014 008 1262 400 0.29 .0 1322 0.069 417.2 892 3745 0.2 348 70.905 124. 77.10 05 3499 029 7383 0274 7900 0275 Carton mononide Caron dionide 93.4 940 44.010 614 0224 3042 Carton disulfide 160. 3194 Hydognde Sulfur dionide 34.O2 0.004 3735 TK4 0.29 122. 127. 64.065 Sulfur ionide 0.424 909 0583 I80.2 K.10 025 640 0251 3179 Nitric anide (NO) 000 1214 Nis aide N0) H013 Hydrogen chloride Hydropen yanide Water 0.141 2096 0132 3247 7245 0274 KA10 029 33.90 0.197 0345 647.1 2055 0229 974 21.026 IKOIS 139. 3732 297 Ammnia Nre d Sulfurk aid 17.031 0.3 105.7 I1230 0212 68.90 0231 61.00 0.7 725 145 177. 0714 S200 ...
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