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Of the following binary liquid/vapor systems, which can be approximately modeled by Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful. (a) Benzene/toluene at 1(atm). (b) n-Hexane/n-heptane at 25 bar. (c) Hydrogen/propane at 200 K. (d) Iso-octane/n-octane at 100°C. (e) Water/n-decane at 1 bar.

Of the following binary liquid/vapor systems, which can be approximately modeled by Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful. (a) Benzene/toluene at 1(atm). (b) n-Hexane/n-heptane at 25 bar. (c) Hydrogen/propane at 200 K. (d) Iso-octane/n-octane at 100°C. (e) Water/n-decane at 1 bar.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Of the following binary liquid/vapor systems, which can be approximately modeled by
Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful.
(a) Benzene/toluene at 1(atm).
(b) n-Hexane/n-heptane at 25 bar.
(c) Hydrogen/propane at 200 K.
(d) Iso-octane/n-octane at 100°C.
(e) Water/n-decane at 1 bar.

Molar z cm't TJK 3224 TK Pbar ma Cyckpentane Cycloherane Mathykyckopentane Mehykyckiheane 70.134 0.196 SILS 45.00 0273 258 0210 5536 3539 020 5328 37 8 0272 0235 572 2123 319. MA 131. 3450 2.004 30.40 021 hopylene -Buene ci-2Butene truna-2-Butene 42 56.08 56.0 INKA 2253 0.19 420.0 0205 435 6 0218 428.6 043 0.277 4243 0.273 41.00 0.275 2393 2769 274.0 231 354 2389 2204 1-Heene 020 S040 0194 417.9 0.190 425 2 31.40 025 4000 0225 4277 0.26 3363 56.08 bobutylene 13-Butadiene 21. 82.145 26.008 78114 92.141 106.167 0212 504 41.50 0272 6139 0271 489 0271 41.06 0.264 36.06 0.263 3561 Cyclobenene Acetylene Benene 0210 52 259. 316. 3532 3838 Toluene Eshylbeneeme Cumene Xylene Xylene Xylene Styrene Naphthalene Biphenyl Formaldelyde Acetaldehyde Mathyl aetate Eyl actte Acetone 000 6172 427. 120 194 106.167 106.167 036 631I 0310 60 036 617.1 32.09 0.264 37.34 0.263 3536 0.299 4256 4176 376 4123 106 67 104 152 12114 154211 0322 6162 02 6MO 748.4 0365 793 35.11 0.20 38.40 0.256 4051 0.2 38.50 0.295 379 352 41A 522 30.006 44.063 74.079 0282 40O 46.0 6590 0223 55.50 0.221 115. 254.1 240 029 0331 154. 47.50 0253 22K. 5233 NO 0.255 2 3502 0.307 SON2 47.01 0.233 41.30 0.249 20 267. 3294 3528 Methyl ettyl ketone Dieyl eher Methyl rutyl ether Methan 72.07 0323 5355 74123 021 6.7 3.40 0.260 150 026 .1 0.564 S126 340 0273 s0.0 0.224 3379 Ethanol 0645 513.9 0622 5368 0.994 563.1 6LAS 0240 S1.75 0254 4423 0.20 167. 3514 3704 1-Propanol 1-Butanol 60.06 74.123 219. 275.
Transcribed Image Text:Molar z cm't TJK 3224 TK Pbar ma Cyckpentane Cycloherane Mathykyckopentane Mehykyckiheane 70.134 0.196 SILS 45.00 0273 258 0210 5536 3539 020 5328 37 8 0272 0235 572 2123 319. MA 131. 3450 2.004 30.40 021 hopylene -Buene ci-2Butene truna-2-Butene 42 56.08 56.0 INKA 2253 0.19 420.0 0205 435 6 0218 428.6 043 0.277 4243 0.273 41.00 0.275 2393 2769 274.0 231 354 2389 2204 1-Heene 020 S040 0194 417.9 0.190 425 2 31.40 025 4000 0225 4277 0.26 3363 56.08 bobutylene 13-Butadiene 21. 82.145 26.008 78114 92.141 106.167 0212 504 41.50 0272 6139 0271 489 0271 41.06 0.264 36.06 0.263 3561 Cyclobenene Acetylene Benene 0210 52 259. 316. 3532 3838 Toluene Eshylbeneeme Cumene Xylene Xylene Xylene Styrene Naphthalene Biphenyl Formaldelyde Acetaldehyde Mathyl aetate Eyl actte Acetone 000 6172 427. 120 194 106.167 106.167 036 631I 0310 60 036 617.1 32.09 0.264 37.34 0.263 3536 0.299 4256 4176 376 4123 106 67 104 152 12114 154211 0322 6162 02 6MO 748.4 0365 793 35.11 0.20 38.40 0.256 4051 0.2 38.50 0.295 379 352 41A 522 30.006 44.063 74.079 0282 40O 46.0 6590 0223 55.50 0.221 115. 254.1 240 029 0331 154. 47.50 0253 22K. 5233 NO 0.255 2 3502 0.307 SON2 47.01 0.233 41.30 0.249 20 267. 3294 3528 Methyl ettyl ketone Dieyl eher Methyl rutyl ether Methan 72.07 0323 5355 74123 021 6.7 3.40 0.260 150 026 .1 0.564 S126 340 0273 s0.0 0.224 3379 Ethanol 0645 513.9 0622 5368 0.994 563.1 6LAS 0240 S1.75 0254 4423 0.20 167. 3514 3704 1-Propanol 1-Butanol 60.06 74.123 219. 275.
Talde KA: Characteritie Properties of ure Species Malar T/K Phar . 't EK Methane Ethane 4599 0.26 48.72 0279 3000 1455 1846 hupane tane -Pentane 4248 0.26 2000 S123 72150 0.300 425.1 0252 4.7 37.96 0274 33.70 0.270 255. 313 2717 302 eane -Heptane kane Nonane 3025 0.26 27.40 0261 240 06 371. 42 3419 3716 100 20 0350 5402 0.00 Ms7 0444 S46 S44. 2190 022 2110 0247 4340 Decane fobutane booctane 0.42 617.7 600 4473 114231 O02 5440 2568 0366 468 3714 APPENTYA Patiof Pare Species Tale BI (Contimed Molar TK Phar cm't TK ma Cyckpentane Cyckibeane Metlhykyckpentane Mehykyckileane 0.196 SILS 45.00 0273 258 3224 0210 553.6 0230 5328 0235 3722 4073 0273 3539 37.85 0272 347I 0. 319. 345.0 394.1 2.004 2123 30.40 0.2 131.
Transcribed Image Text:Talde KA: Characteritie Properties of ure Species Malar T/K Phar . 't EK Methane Ethane 4599 0.26 48.72 0279 3000 1455 1846 hupane tane -Pentane 4248 0.26 2000 S123 72150 0.300 425.1 0252 4.7 37.96 0274 33.70 0.270 255. 313 2717 302 eane -Heptane kane Nonane 3025 0.26 27.40 0261 240 06 371. 42 3419 3716 100 20 0350 5402 0.00 Ms7 0444 S46 S44. 2190 022 2110 0247 4340 Decane fobutane booctane 0.42 617.7 600 4473 114231 O02 5440 2568 0366 468 3714 APPENTYA Patiof Pare Species Tale BI (Contimed Molar TK Phar cm't TK ma Cyckpentane Cyckibeane Metlhykyckpentane Mehykyckileane 0.196 SILS 45.00 0273 258 3224 0210 553.6 0230 5328 0235 3722 4073 0273 3539 37.85 0272 347I 0. 319. 345.0 394.1 2.004 2123 30.40 0.2 131.
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