Of the following binary liquid/vapor systems, which can be approximately modeled byRaoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful.(a) Benzene/toluene at 1(atm).(b) n-Hexane/n-heptane at 25 bar.(c) Hydrogen/propane at 200 K.(d) Iso-octane/n-octane at 100°C.(e) Water/n-decane at 1 bar. Molarz cm't TJK3224TK PbarmaCyckpentaneCycloheraneMathykyckopentaneMehykyckiheane70.1340.196 SILS45.00 02732580210 55363539020 5328 37 8 02720235 5722123319.MA131.34502.00430.40 021hopylene-Bueneci-2Butenetruna-2-Butene4256.0856.0INKA22530.19420.00205 435 60218 428.6043 0.2774243 0.27341.00 0.27523932769274.0231354238922041-Heene020 S0400194 417.90.190 425 231.40 0254000 02254277 0.26336356.08bobutylene13-Butadiene21.82.14526.0087811492.141106.1670212 50441.50 02726139 0271489 027141.06 0.26436.06 0.2633561CyclobeneneAcetyleneBenene0210 52259.316.35323838TolueneEshylbeneemeCumeneXyleneXyleneXyleneStyreneNaphthaleneBiphenylFormaldelydeAcetaldehydeMathyl aetateEyl actteAcetone000 6172427.120 194106.167106.167036 631I0310 60036 617.132.09 0.26437.34 0.2633536 0.299425641763764123106 67104 152121141542110322 616202 6MO748.40365 79335.11 0.2038.40 0.2564051 0.238.50 0.29537935241A52230.00644.06374.0790282 40O46.06590 022355.50 0.221115.254.12400290331154.47.50 025322K.5233NO 0.255235020.307SON247.01 0.23341.30 0.24920267.32943528Methyl ettyl ketoneDieyl eherMethyl rutyl etherMethan72.070323 5355741230216.73.40 0.260150026 .10.564 S126340 0273s0.0 0.2243379Ethanol0645 513.90622 53680.994 563.16LAS 0240S1.75 02544423 0.20167.351437041-Propanol1-Butanol60.0674.123219.275. Talde KA: Characteritie Properties of ure SpeciesMalarT/K Phar . 't EKMethaneEthane4599 0.2648.72 0279300014551846hupanetane-Pentane4248 0.262000S123721500.300 425.10252 4.737.96 027433.70 0.270255.3132717302eane-HeptanekaneNonane3025 0.2627.40 0261240 06371.4234193716100 200350 54020.00 Ms70444 S46S44.2190 0222110 02474340Decanefobutanebooctane0.42 617.76004473114231 O02 5440 2568 0366 4683714APPENTYA Patiof Pare SpeciesTale BI (ContimedMolarTK Pharcm't TKmaCyckpentaneCyckibeaneMetlhykyckpentaneMehykyckileane0.196 SILS45.00 027325832240210 553.60230 53280235 37224073 0273353937.85 0272347I 0.319.345.0394.12.004212330.40 0.2131.

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Answered: Of the following binary liquid/vapor…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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Question

Of the following binary liquid/vapor systems, which can be approximately modeled by
Raoult’s law? For those that cannot, why not? Table B.1 (App. B) may be useful.
(a) Benzene/toluene at 1(atm).
(b) n-Hexane/n-heptane at 25 bar.
(c) Hydrogen/propane at 200 K.
(d) Iso-octane/n-octane at 100°C.
(e) Water/n-decane at 1 bar.

Molar
z cm't TJK
3224
TK Pbar
ma
Cyckpentane
Cycloherane
Mathykyckopentane
Mehykyckiheane
70.134
0.196 SILS
45.00 0273
258
0210 5536
3539
020 5328 37 8 0272
0235 572
2123
319.
MA
131.
3450
2.004
30.40 021
hopylene
-Buene
ci-2Butene
truna-2-Butene
42
56.08
56.0
INKA
2253
0.19
420.0
0205 435 6
0218 428.6
043 0.277
4243 0.273
41.00 0.275
2393
2769
274.0
231
354
2389
2204
1-Heene
020 S040
0194 417.9
0.190 425 2
31.40 025
4000 0225
4277 0.26
3363
56.08
bobutylene
13-Butadiene
21.
82.145
26.008
78114
92.141
106.167
0212 504
41.50 0272
6139 0271
489 0271
41.06 0.264
36.06 0.263
3561
Cyclobenene
Acetylene
Benene
0210 52
259.
316.
3532
3838
Toluene
Eshylbeneeme
Cumene
Xylene
Xylene
Xylene
Styrene
Naphthalene
Biphenyl
Formaldelyde
Acetaldehyde
Mathyl aetate
Eyl actte
Acetone
000 6172
427.
120 194
106.167
106.167
036 631I
0310 60
036 617.1
32.09 0.264
37.34 0.263
3536 0.299
4256
4176
376
4123
106 67
104 152
12114
154211
0322 6162
02 6MO
748.4
0365 793
35.11 0.20
38.40 0.256
4051 0.2
38.50 0.295
379
352
41A
522
30.006
44.063
74.079
0282 40O
46.0
6590 0223
55.50 0.221
115.
254.1
240
029
0331
154.
47.50 0253
22K.
5233
NO 0.255
2
3502
0.307
SON2
47.01 0.233
41.30 0.249
20
267.
3294
3528
Methyl ettyl ketone
Dieyl eher
Methyl rutyl ether
Methan
72.07
0323 5355
74123
021
6.7
3.40 0.260
150
026 .1
0.564 S126
340 0273
s0.0 0.224
3379
Ethanol
0645 513.9
0622 5368
0.994 563.1
6LAS 0240
S1.75 0254
4423 0.20
167.
3514
3704
1-Propanol
1-Butanol
60.06
74.123
219.
275.

Talde KA: Characteritie Properties of ure Species
Malar
T/K Phar . 't EK
Methane
Ethane
4599 0.26
48.72 0279
3000
1455
1846
hupane
tane
-Pentane
4248 0.26
2000
S123
72150
0.300 425.1
0252 4.7
37.96 0274
33.70 0.270
255.
313
2717
302
eane
-Heptane
kane
Nonane
3025 0.26
27.40 0261
240 06
371.
42
3419
3716
100 20
0350 5402
0.00 Ms7
0444 S46
S44.
2190 022
2110 0247
4340
Decane
fobutane
booctane
0.42 617.7
600
4473
114231 O02 5440 2568 0366 468
3714
APPENTYA Patiof Pare Species
Tale BI (Contimed
Molar
TK Phar
cm't TK
ma
Cyckpentane
Cyckibeane
Metlhykyckpentane
Mehykyckileane
0.196 SILS
45.00 0273
258
3224
0210 553.6
0230 5328
0235 3722
4073 0273
3539
37.85 0272
347I 0.
319.
345.0
394.1
2.004
2123
30.40 0.2
131.

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