Please solve Starting with the differential form of the Helmholtz free energy F, deriveand thusOFᎢOF= -Sand= -PᏙV(as=avUse the expression derived in part a to determine the change in entropy when one mol ofmercury is compressed from an initial start = 1 x 104 m³ to a final volume Vend = 2 × 10 5 m³.Assume the mercury obeys the Van der Waals equation for a non-ideal gas,RTaP =V-bfor mercury: a = 0.8200m Pa and b = 1.696 x 10 m³.

Step 1: Step 2: Step 3: Step 4:

Answered: Starting with the differential form of…

University Physics Volume 2

18th Edition

ISBN:9781938168161

Author:OpenStax

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Chapter4: The Second Law Of Thermodynamics

Section: Chapter Questions

Problem 86CP: A cylinder contains 500 g of helium at 120 atm and 20 . The valve is leaky, and all the gas slowly...

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A monatomic ideal gas undergoes a quasi-static process that is described by the function pV=p1+3(vv1) , where the stating state is (p1,v1) and the final state (p2,v2) . Assume the system consists of n moles of the gas in a container that can exchange heat with the environment and whose volume can change freely. (a) Evaluate the work done by the gas during the change in the state. (b) Find the change in internal energy of the gas. (c) Find the heat input to the gas during the change. (d) What ale initial and final temperatures?
A copper rod of cross-sectional area 5.0 cm2 and length 5.0 m conducts heat from a heat reservoir at 373 K to one at 273 K. What is the time rate of change of the universe's entropy for this process?
Two moles of a monatomic ideal gas such as oxygen is compressed adiabatically and reversibly from a state (3 atm, 5 L) to a state with a pressure of 4 atm. (a) Find the volume and temperature of the final state. (b) Find the temperature of the initial state. (c) Find work done by the gas in the process. (d) Find the change in internal energy in the process. Assume Cv=5R and Cp=Cv+R for the diatomic ideal gas in the conditions given.
An ideal gas at temperature T is stored in the left half of an insulating container of volume V using a partition of negligible volume (see below). What is the entropy change per mole of the gas in each of the following cases? (a) The partition is suddenly removed and the gas quickly fills the entire container. (b) A tiny hole is punctured in the partition and after a long period, the gas reaches an equilibrium state such that there is no net flow through the hole. (c) The partition is moved very slowly and adiabatically all the way to the light wall so that the gas finally fills the entire container.
Assume a sample of an ideal gas is at room temperature. What action will necessarily make the entropy of the sample increase? (a) Transfer energy into it by heat. (b) Transfer energy into it irreversibly by heat. (c) Do work on it. (d) Increase either its temperature or its volume, without letting the other variable decrease. (e) None of those choices is correct.
Two hundred grams of water at 0 is brought into contact into thermal equilibrium successively with reservoirs at 20 , 40 , 60 , and 80 . (a) What is the entropy change of the water? (b) Of the reservoir? (c) What is the entropy change of the universe?
Consider an ideal gas Joule cycle, also called the Brayton cycle, shown below. Find the formula for efficiency of the engine using this cycle in terms of P1 , P2 and .
(a) infinitesimal amount of heat is added reversibly to a system. By combining the first and second laws, show that dU=TdSdW. (b) When heat is added to an ideal gas, its temperature and volume change from T1 and V1 to T2 and V2 . Show that the entropy change of n moles of the gas is given by S=CnvlnT2T1nRlnV2V1 .
One process for decaffeinating coffee uses carbon dioxide ( M=44.0 g/mol) at a molar density of about 14,0 mol/m3 and a temperature of about 60 . (a) Is CO2 a solid, liquid, gas, or supercritical fluid under those conditions? (b) The van der Waals constants for carbon dioxide are a=0.3658 Pa m6/mol2 and b=4.286105 m3/mol. Using the van der Waals equation, estimate pressure of CO2 at that temperature and density. `
Find the work done in the quasi-static processes shown below. The states are given as (p, V) values for the points in the PV plane: 1 (3 atm, 4 L), 2 (3 atm, 6 L), 3 (5 atm, 4 L), 4 (2 atm, 6 L), 5 (4 atm, 2 L), 6 (5 atm, 5 L) and 7 (2 atm, 5 L).
(a) A 5.0-kg rock at a temperature of 20 is dropped into a shallow lake also at 20 from a height of 1.0103 m. What is the resulting change in entropy of the universe? (b) If the temperature of the lock is 100 when it is dropped, what is the change of entropy of the universe? Assume that air friction is negligible (not a good assumption) and that c=860 J/kg K is the specific heat of the rock.
The temperature of n moles of an ideal gas changes from T1 to T2 in a quasi-static adiabatic transition. Show that the work done by the gas is given by W=nR1(T1T2).

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