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Rank the following molecules in order of increasing relative rate of SN1 Solvolysis with methanol and heat

Rank the following molecules in order of increasing relative rate of SN1 Solvolysis with methanol and heat

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Rank the following molecules in order of increasing relative rate of SN1 Solvolysis with methanol and heat
В PROR СН3 A) CHỖ CHICHCH3 ВЈCH3-CH2-CH2-CHle - Bir Cl c CH3-CH2-CH2- сн - CH₂ D) CH3 -CH₂-CH₂-C-CH3 I -CH3 Br
Transcribed Image Text:В PROR СН3 A) CHỖ CHICHCH3 ВЈCH3-CH2-CH2-CHle - Bir Cl c CH3-CH2-CH2- сн - CH₂ D) CH3 -CH₂-CH₂-C-CH3 I -CH3 Br
Expert Solution
Step 1

The concept of the question is taken from general Organic chemistry. 

According to question.

1) Rate of SN1 reaction is directly proportional to stability of carbocation formed. 

Benzyl > Allyl > 3° > 2° >1° > Methyl. 

2)  Rate of solvolysis From different Halogen are. 

I > Br > Cl > F

 

The detailed solution is done below. 

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