4. The cell potentials of many oxidation-reduction reactions are highly dependent on pH. Consider the following equation: 3 Co(s) + 2NO3(aq) + 8 H+ (aq) -----> 3 Co2+ (aq) + 2NO(g) + 4H₂O(1) a) Determine the standard cell potential for the reaction. b) What would be the pH of the solution at standard conditions? (HINT: What are the concentrations of all aqueous species at standard conditions?) c) Determine the cell potential for the reaction at a pH of_2.0. (Hint: You will need to use the Nernst equation.) Assume that all concentrations, other than that of H*, are standard. d) Based on your answers above, would you say that the reaction is more favorable (i.e., more spontaneous) at higher pH or lower pH? Explain.
4. The cell potentials of many oxidation-reduction reactions are highly dependent on pH. Consider the following equation: 3 Co(s) + 2NO3(aq) + 8 H+ (aq) -----> 3 Co2+ (aq) + 2NO(g) + 4H₂O(1) a) Determine the standard cell potential for the reaction. b) What would be the pH of the solution at standard conditions? (HINT: What are the concentrations of all aqueous species at standard conditions?) c) Determine the cell potential for the reaction at a pH of_2.0. (Hint: You will need to use the Nernst equation.) Assume that all concentrations, other than that of H*, are standard. d) Based on your answers above, would you say that the reaction is more favorable (i.e., more spontaneous) at higher pH or lower pH? Explain.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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![4. The cell potentials of many oxidation-reduction reactions are highly dependent on pH.
Consider the following equation:
3 Co(s)
+ 2 NO3(aq) + 8 H+ (aq) -----> 3 Co²+ (aq) +
+(aq) + 2 NO(g) + 4H₂O)
a) Determine the standard cell potential for the reaction.
b) What would be the pH of the solution at standard conditions? (HINT: What are the
concentrations of all aqueous species at standard conditions?)
c) Determine the cell potential for the reaction at a pH of_2.0. (Hint: You will need to
use the Nernst equation.) Assume that all concentrations, other than that of H*, are standard.
d) Based on your answers above, would you say that the reaction is more favorable (i.e., more
spontaneous) at higher pH or lower pH? Explain.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1105d6c6-0de2-4d8b-8a94-e6a54edf7006%2F3d5b8347-fe25-4914-bf21-c160ec57e57f%2Fr1xvgs_processed.jpeg&w=3840&q=75)
Transcribed Image Text:4. The cell potentials of many oxidation-reduction reactions are highly dependent on pH.
Consider the following equation:
3 Co(s)
+ 2 NO3(aq) + 8 H+ (aq) -----> 3 Co²+ (aq) +
+(aq) + 2 NO(g) + 4H₂O)
a) Determine the standard cell potential for the reaction.
b) What would be the pH of the solution at standard conditions? (HINT: What are the
concentrations of all aqueous species at standard conditions?)
c) Determine the cell potential for the reaction at a pH of_2.0. (Hint: You will need to
use the Nernst equation.) Assume that all concentrations, other than that of H*, are standard.
d) Based on your answers above, would you say that the reaction is more favorable (i.e., more
spontaneous) at higher pH or lower pH? Explain.
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Follow-up Question
For part, b would the calculations be the same for NO3^- (aq) and CO^2+ (aq), meaning those species PH would also equal 0?
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Follow-up Question
Why is the reaction more favorable at lower pH?
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