Answered: A) Rank the following molecules in…

A) Rank the following molecules in order of decreasing rate of SN1 solvolysis (1 is fastest, 4 is slowest). Briefly explain. O₂N MeO H3C CI MeO CI

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.7: Sigmatropic Rearrangements

Problem 7P

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Question

explain part A by first drawing all the resonance structures for the four compounds please. and then write the explanaiton. HANDDRAW it instead of using text. thanks

A) Rank the following molecules in order of decreasing rate of SN1 solvolysis (1 is fastest, 4 is
slowest). Briefly explain.
CI
H3C
I More H₂ve
]
O
O₂N
OH
MeO
Rank the following indicated alcohols in the below molecule in order of decreasing rate of
oxidation with MnO2 (1 is fastest, 3 is slowest). Briefly explain.
OH OH
00
O

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