Rank the carbocations in the table below in order of decreasing stability (1 most stable and 4 least stable). + HO. N. + + (Choose one) (Choose one) (Choose one) (Choose one)
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- 3. Rank the following carbocations in order of increasing stability. (1 = least stable, 5 = most stable)3. Draw the intermediate carbocation that is formed when each is protonated, say, with H*. These occur when adding HBr, HCI, HI, or H*/H2O to a double bond. The rich get richer. will it rearrange? will it rearrange? will it rearrange? will it rearrange? will it rearrange? will it rearrange?Rank the following carbocations, from least stable (left) to most stable (right). ou oe i. ii. ii. O i. < ii. < ii. O ii. < i. < ii. O iii. < ii. < i. O i. < iii. < ii. O ii. < iii. < i.
- Which carbocation below is/are the most stable one? Circle it (them)2. Draw the pi molecular orbitals, fill in the correct number of pi electrons, and label the HOMO and LUMO. (+ 3. Circle three allylic carbons in thiamine to the right. How many allylic hydrogens does it have? Why is the indicated carbon not allylic? thiamine `N `N NH₂ -ОН # allylic HsRank the carbocations in the table below in order of increasing stability (1 least stable and 4 most stable). ? NH₂ X X (Choose one) Explanation A S Check ▼ + (Choose one) 1- least stable 2 3 4- most stable Q Search + (Choose one) ly NH, (Choose one) + ▼ 2023 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Acc
- 4. Rank the following carbocations according to stability (1: most stable, 5: least stable.). ht t tá OCH 3 +2. For the following nucleophilic substitution reaction: NaOC(CH3)3 CH3 'CH3 CH3 a. Draw the first transition state (TS1), the reaction intermediate, and the second m transition state (TS2) in the labeled boxes. Make sure to show any formal charges, unfilled p-orbitals, and correct stereochemistry. TS₁ 41001 Intermediate ogmos TS2 amond- b. Which of three molecules you drew for part 'a' is lowest in energy? Write your answer in the box below. c. Draw the product(s) of the nucleophilic addition reaction shown. Make sure to use wedged and dashed lines to clearly show the resulting stereochemistry at each chiral center. If there is more than one possible product, draw one in each box - if not, leave one box blank. CH3 Br + NaOC(CH3)3sino omoH SART 3. a. Rank the following based on stability, least to most stable (1 is the least stable; 3 is the most stable). Jombon nieco Co digidivory boon toy tarimoges vas bus fiat od 4700 b. Circle the molecule in part a that has the largest heat of hydrogenation (AHhydrogenation). 4. As shown below, compound 2 can be made from compound 1 in two steps. Provide the reagents, A, and draw the product B for the first step. Then, provide the reagents C that lead to
- 6. The Newman projection and an equivalent 3D projection for an alkyl bromide is shown below. Under E2 conditions, there is only one major alkene product. Ph H3C H H3C. H H Br CH₂CH3 = Ph. H Br E2 conditions major product a. In 1-2 sentences, explain why only one constitutional isomer (regioisomer) forms. b. Explain why only one stereoisomer is possible for this E2 reaction. In your explanation, draw the conformation of the alkyl bromide that reacts to form product.9. Rank the carbocations below in order of increasing stability (least stable - 1; most stable - 3). Place the number corresponding to the carbocation's relative stability in the blank below the structure.7. Which of the following carbocations is most stable (circle your answer)