Predict the geometry for all atoms (except hydrogen) in the compound below: HIIO-H H-C C-H H H-C H H HIHI CIN ## H-CC-H TH H-C H H H-C-H H-C C-H (a) H H (b) Identify whether each of the following compounds exhibits a molecular dipole moment. For compounds that do, indicate the direction of the net molecular dipole moment: (a) CHCl3 (b) CH3OCH3 (c) NH3 (d) CCl₂Br2
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- Acetyl salicylic acid (aspirin), the most widely used medi-cine in the world, has the Lewisstructure at right. (a) What is the hybridization of each C and each O atom? (b) How many localized π bonds are present? (c) How many C atoms have a trigonal planar shape around them? A tetra hedral shape?Octocrylene is an ingredient found in topical sunscreens. It is a water-resistant molecule that helps protect skin against harmful UVA and UVB radiation. (a) What is the hybridization of each nonhydrogen atom? (b) Circle all atoms bonded to the acyclic C=C double bond that are required to be in the same plane. (c) Are there two unique configurations possible about the acyclic C=C double bond? Explain. (d) Which of the two C-C single bonds indicated by arrows would you expect to be shorter? Explain. OctocryleneWhich compound in each of the following pairs would you expect to have the greaterdipole moment μ? Why?(a) HF or HCl (d) CHCl3 or CCl3F(b) HF or BF3 (e) CH3NH2 or CH3OH(c) (CH3)3CH or (CH3)3CCl (f) CH3NH2 or CH3NO2
- The O¬H bond lengths in the water molecule (H2O) are0.96 Å, and the H—O—H angle is 104.5°. The dipole momentof the water molecule is 1.85 D. (a) In what directionsdo the bond dipoles of the O—H bonds point? In what directiondoes the dipole moment vector of the water moleculepoint? (b) Calculate the magnitude of the bond dipoleof the O—H bonds. (Note: You will need to use vector addition to do this.) (c) Compare your answer from part (b)to the dipole moments of the hydrogen halides (Table 8.3).Is your answer in accord with the relative electronegativityof oxygen?Octocrylene is an ingredient found in topical sunscreens. It is a water-resistant molecule that helps protect skin against harmful UVA and UVB radiation. Octocrylene Please answer the following questions: (a) What is the hybridisation of each nonhydrogen atom? (b) Are there two unique configurations possible about the C=C double bond? Please explain your answer. (c) Which of the two C-C bonds indicated by the arrows would you expect to be shorte.? Please explain your answer.Which molecule in each pair has the greater dipole moment? Give the reason for your choice. (a) ClO2 or SO2 (b) HBr or HCl (c) BeCl2 or SCl2 (d) AsF3 or AsF5
- Which molecule in each pair has the greater dipole moment?Give the reason for your choice.(a) ClO2 or SO2 (b) HBr or HCl(c) BeCl2 or SCl2 (d) AsF3 or AsF5Complete the following table: Lewis structure atoms: bonds between orbitals making each total bond order hybridization atoms: type E valence bond: between two atoms |Н: 1s C and H: o sp?(C) + 1s(H) C and H: 1 C: sp? Cl: sp3 0: sp? :0: || C and Cl: o sp?(C) + sp°(CI) C and Cl: 1 = sp?(C) + sp²(0) = p(C) + p(0) C and O: o C and O: 2 CI C and O: t C: C and C: C and C: C and C: C: H-C=C-H H: C and H: C and C: H: C and H: N: N and I: N and I: N= I: N and I: C: C and Cl: C and Cl: :Cl Cl: C and Cl: C and Cl: Cl: C and Cl: -c=cl: C and Cl: :Z: :U:Dichloroethylene (C2H2Cl2) has three forms (isomers), eachof which is a different substance. (a) Draw Lewis structures ofthe three isomers, all of which have a carbon–carbon doublebond. (b) Which of these isomers has a zero dipole moment?(c) How many isomeric forms can chloroethylene, C2H3Cl,have? Would they be expected to have dipole moments?
- Among the most common over-the-counter drugs you might find in a medicine cabinet are mild pain relievers such ibuprofen (Advil, Motrin) and naproxen (Aleve). H3C он HO, Ibuprofen Naproxen (a) How many sp3-hybridized carbons does each molecule have? (b) How many sp2-hybridized carbons does each molecule have? (c) Can you spot any similarities in their structures?Butadiene, C4H6, is a planar molecule that has the followingcarbon–carbon bond lengths:(a) Predict the bond angles around each of the carbon atomsand sketch the molecule. (b) From left to right, whatis the hybridization of each carbon atom in butadiene?(c) The middle C¬C bond length in butadiene (1.48 Å) isa little shorter than the average C¬C single bond length(1.54 Å). Does this imply that the middle C¬C bond in butadieneis weaker or stronger than the average C¬C singlebond? (d) Based on your answer for part (c), discuss what additional aspects of bonding in butadiene might supportthe shorter middle C¬C bond.Which molecule in each pair has the greater dipole moment? Give the reason for your choice.(a) SO2 or SO3 (b) ICl or IF(c) SiF4 or SF4 (d) H2O or H2S