POST LAB Name 1. Judging from your experimental rate law (uncatalyzed) and given the mechanism below, which step is rate determining? Label each substance as reactant (R1, R2), product (P1,P2), or intermediate (I). a. IS20² → ISO4 + 804²- b. I + ISO4 → 12 + 804² 2. Derive the rate law for the mechanism proposed below for the catalyzed reaction. Label each substance as reactant (R1, R2), product(P1,P2), intermediate (I1, 12, 13), or catalyst (C). a) I + Cu²+ ←→ Cul+ fast (to steady state) + b) c) 2 Cul 2 Cu + I2 S₂Og² + CuSO4 + SO4² + Cu²+ (fast) + d) Cu + S04 → SO² + Cu²+ (slow) (fast)

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Chapter1: Chemical Foundations
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POST LAB
Name
1. Judging from your experimental rate law (uncatalyzed) and given the mechanism
below, which step is rate determining? Label each substance as reactant (R1, R2),
product (P1,P2), or intermediate (I).
a.
IS20² → ISO4
+ 804²-
b. I + ISO4 → 12 + 804²
2. Derive the rate law for the mechanism proposed below for the catalyzed reaction.
Label each substance as reactant (R1, R2), product(P1,P2), intermediate (I1, 12, 13),
or catalyst (C).
a)
I + Cu²+
←→ Cul+
fast (to steady state)
+
b)
c)
2 Cul 2 Cu + I2
S₂Og² + CuSO4 + SO4² + Cu²+
(fast)
+
d)
Cu + S04 → SO² + Cu²+
(slow)
(fast)
Transcribed Image Text:POST LAB Name 1. Judging from your experimental rate law (uncatalyzed) and given the mechanism below, which step is rate determining? Label each substance as reactant (R1, R2), product (P1,P2), or intermediate (I). a. IS20² → ISO4 + 804²- b. I + ISO4 → 12 + 804² 2. Derive the rate law for the mechanism proposed below for the catalyzed reaction. Label each substance as reactant (R1, R2), product(P1,P2), intermediate (I1, 12, 13), or catalyst (C). a) I + Cu²+ ←→ Cul+ fast (to steady state) + b) c) 2 Cul 2 Cu + I2 S₂Og² + CuSO4 + SO4² + Cu²+ (fast) + d) Cu + S04 → SO² + Cu²+ (slow) (fast)
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