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Order-disorder phenomena
a) do not have conductive properties.
b) are cooperative.
c) have few industrial implications.
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- a.) Slove for the Gibbs energy of formation for a generic compound AB2 in kJ/mol given the following thermodynamic data. ΔfH∘kJ/mol Sf∘ J/mol K A(l) 0 75 B2(g) 0 220 AB2(s) -200 140 b. According the result from a, will the formation of AB2(s) occur under standard state conditions? Why or why not?Consider the dissolution of NaBr and NaI. The values provided here will be helpful for answering the following questions. ΔH∘solnΔHsoln∘ (kJ/mol) ΔS∘solnΔSsoln∘ Jmol•KNaBr –0.860 57.0NaI –7.50 74.0 Write a balanced equilibrium equation for the dissolution of NaI in water. Include phases. Which of the following explains why the entropy change is greater for the dissolution of NaI compared to the dissolution of NaBr?Choose one: A. The interactions between bromide ions with other bromide ions is stronger than the interactions between iodide ions with other iodide ions. B. The cation forms stronger ion-dipole networks with water in NaBr than NaI because of the weaker bond to Br.C. The more negative change in enthalpy observed with NaI implies greater dissociation and hence greater entropy.D. Iodide has weaker ion-dipole interactions with…a. Calculate the Gibbs energy of formation for a generic compound AB2 in kJ/mol given the following thermodynamic data A;H° kJ/mol S; J/mol K A(I) B2(g) AB2(s) 76.02 223.07 |-224.3 146.00 b. Interpret your result from part a. Will the formation of AB2(s) occur under standard state conditions? Why or why not?
- (c) Define self-assembly in supramolecular chemistry. Explain the metal-directed self-assembly process by taking a suitable example.(b) Line defects or dislocations are abrupt change in atomic order along a line. A dislocation is the defect responsible for the phenomenon of slip, by which most metals deform plastically. One of the types is Screw Dislocation. Sketch and explain the Screw dislocation line defects. ANSWER:What does entryopy do in catalysis by proximity effects..?
- Q2: Consider a molecular interaction denoted as X-HY, where "-" signifies a covalent bond and "..." indicates hydrogen bonding. The system can be described as a superposition of three structures: |X-HY-)= V1+s 1 0 (s) |X:, H+,: Y-) = (1); |X:-, H-Y) = 0 0 0 (s), 1 where 0 < s << 1. The first (last) structure represents a pure covalent bond between the atoms X (Y) and H, with Y (X) carrying a negative charge. The middle structure depicts an ionic configuration where X and Y bear negative charges, while H carries a positive charge. In this structure, there is no covalent bond. The Hamiltonian for this molecular system reads 0 0 2€ 2€ 0 H=(0 -E မဝါဝ I a) Determine the expected energies for the covalent structures IX-H, Y) and (X:-, H-Y). b) Calculate the expected energy for the ionic structure IX: H: Y) and compare its stability with the covalent structures.In a vacuum chamber filled with argon gas at 100 mTorr, a plasma is ignited resulting to 1% ionization. This is already a "hot plasma" by lab processing standards. Calculate the number density of plasma electrons (should be about the same as the argon ion density due to quasineutrality) in this 1% ionized plasma.Why is the Fe-Fe3-C phase diagram a metastable phase diagram instead of a true equilibrium phase diagram? (b) Define the following phases that exist in the Fe-Fe3-C phase diagram: (i) austenite, (ii) ferrite, (iii) cementite, (iv) ferrite.
- 2. (d) Describe three of the functions of the matrix in fibrereinforced composites. (e) With the aid of sketches compare and contrast the fatigue fracture appearance between an alloy that failed at a low fatigue load and one that failed at a high fatigue load. (f) Propose and briefly describe one non-destructive method that can be used to detect small cracks on the surface of a metallic alloy .Briefly explain the following paragraph: both the distortion of symmetry and the fact that the solid is diamagnetic indicate the existence of a Nb-Nb bond.From the data in Table 14.2, predict B for DCl D is 2H.

